A Systematic Study of the Complexation of Di- and Tri-Valent Lanthanide Ions by Macrocycles of Varying Size
作者： Jean F. Desreux , Jean Massaux
DOI: 10.1007/978-1-4613-3406-4_15
关键词: Anhydrous 、 Crown ether 、 Lanthanide 、 Alkali metal 、 Polymer chemistry 、 Inorganic chemistry 、 Chemistry 、 Propylene carbonate 、 Ion 、 Stability constants of complexes
摘要: Despite the extensive chemistry reported for complexes between a host of macrocyclic compounds and alkali metal ions (1), only limited number lanthanide (Ln) have been studied so far. Some unusual features complexation Ln in anhydrous propylene carbonate by eighteen-membered cycle di-tert-butylbenzo-18-crown-6, 4, recently authors (2). This study has now extended to macrocycles 1–5(see Figures 1 2 structure ligands).
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