Rapid authentication of Pseudostellaria heterophylla (Taizishen) from different regions by near‐infrared spectroscopy combined with chemometric methods

作者: Wei Pan , Mei Wu , Zhenzhu Zheng , Longhua Guo , Zhenyu Lin

DOI: 10.1111/1750-3841.15171

关键词: Sampling (statistics)Partial least squares regressionMathematicsLinear discriminant analysisArtificial intelligencePattern recognitionAuthenticationPseudostellariaNear-infrared spectroscopy

摘要: Pseudostellaria heterophylla is a very popular traditional Chinese medicine herb, also called "Taizishen." Discrimination of P. from different regions critical for ensuring the effectiveness drug use, because effects are diversity each other. To discriminate rapidly and effectively, model extracted by competitive adaptive reweighted sampling (CARS) was established. Original spectra in wave number range 10,000 to 4,000 cm-1 were acquired. Orthogonal partial least squares discriminant analysis (OPLS-DA) used establish suitable model. CARS performed extracting key variables. We found that near-infrared spectrum series samples analyzed Row-center-SG, CARS, OPLS-DA can effectively distinguish regions, accuracy satisfactory terms good discrimination rate. These results show be identify regions. PRACTICAL APPLICATION: According our research results, we draw conclusion may those places origin powder with similar appearance.

参考文章(25)
Guo Tang, Yue Huang, Kuangda Tian, Xiangzhong Song, Hong Yan, Jing Hu, Yanmei Xiong, Shungeng Min, A new spectral variable selection pattern using competitive adaptive reweighted sampling combined with successive projections algorithm. Analyst. ,vol. 139, pp. 4894- 4902 ,(2014) , 10.1039/C4AN00837E
Marzena Jamrógiewicz, Application of the near-infrared spectroscopy in the pharmaceutical technology Journal of Pharmaceutical and Biomedical Analysis. ,vol. 66, pp. 1- 10 ,(2012) , 10.1016/J.JPBA.2012.03.009
Hao Lin, Jiewen Zhao, Quansheng Chen, Fang Zhou, Li Sun, Discrimination of Radix Pseudostellariae according to geographical origins using NIR spectroscopy and support vector data description. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 79, pp. 1381- 1385 ,(2011) , 10.1016/J.SAA.2011.04.072
Hongdong Li, Yizeng Liang, Qingsong Xu, Dongsheng Cao, Key wavelengths screening using competitive adaptive reweighted sampling method for multivariate calibration. Analytica Chimica Acta. ,vol. 648, pp. 77- 84 ,(2009) , 10.1016/J.ACA.2009.06.046
C.K. Wong, K.N. Leung, K.P. Fung, Y.M. Choy, The immunostimulating activities of anti-tumor Polysaccharides from Pseudostellaria heterophylla Immunopharmacology. ,vol. 28, pp. 47- 54 ,(1994) , 10.1016/0162-3109(94)90038-8
Yan Shen, Chao Han, Jidong Liu, Aili Liu, Xiaowu Ji, Cuiping Liu, Analysis of Volatile Components of Pseudostellaria heterophylla (Miq.) Pax by Microwave-Assisted Solvent Extraction and GC–MS Chromatographia. ,vol. 68, pp. 679- 682 ,(2008) , 10.1365/S10337-008-0731-2