Dioxygenation of cysteamine to hypotaurine at a tris(pyrazolyl)borate iron(II) unit – cysteamine dioxygenase mimicking?
作者： M. Sallmann , B. Braun , C. Limberg
DOI: 10.1039/C5CC01083G
关键词: Photochemistry 、 Active site 、 Stereochemistry 、 Hypotaurine 、 Tris 、 Chemistry 、 Cysteamine dioxygenase 、 Cysteamine
摘要: A novel complex TpMe,PhFe(SCH2CH2NH2) has been synthesized as a speculative model for ADO. Indeed its reaction with O2 led to the dioxygenation of S atom and thus hypotaurine. This finding may allow us draw conclusions on constitution ADO active site, whose structure is still unknown.
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