Synthesis and structure of [M(N-methylimidazole)6]S8 (M = Mn, Fe, Ni, Mg). Polysulfide salts prepared by the reaction N-methylimidazole + metal powder + sulfur

作者： Somanath. Dev , Emannuel. Ramli , Thomas B. Rauchfuss , Scott R. Wilson

关键词: Nickel 、 Crystal structure 、 X-ray crystallography 、 Metal powder 、 Sulfur 、 Manganese 、 Magnesium 、 Nuclear chemistry 、 Inorganic chemistry 、 Polysulfide 、 Chemistry

摘要: Powdered magnesium, manganese, iron, and nickel were found to dissolve in N-methylimidazole (N-MeIm) solutions of elemental sulfur give red-colored salts [M(N-MeIm) 6 ]S 8 . The structure the complex was determined by single-crystal X-ray diffraction. compound crystallizes triclinic space group P1

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Synthesis and structure of [M(N-methylimidazole)6]S8 (M = Mn, Fe, Ni, Mg). Polysulfide salts prepared by the reaction N-methylimidazole + metal powder + sulfur

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Synthesis and structure of [M(N-methylimidazole)6]S8 (M = Mn, Fe, Ni, Mg). Polysulfide salts prepared by the reaction N-methylimidazole + metal powder + sulfur

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