Convenient, low-energy synthesis of metal sulfides and selenides; PbE, Ag2E, ZnE, CdE (E = S, Se)

作者: G. Henshaw , I. P. Parkin , G. Shaw

DOI: 10.1039/CC9960001095

关键词:

摘要: Reaction of elemental metal Pb, Ag, Zn and Cd with sulfur or selenium in liquid ammonia at room temperature for 2–12 h produces highly crystalline PbS, PbSe, Ag2S, Ag2Se and X-ray …

参考文章(9)
Philippe R. Bonneau, Robert F. Jarvis, Richard B. Kaner, Rapid solid-state synthesis of materials from molybdenum disulphide to refractories Nature. ,vol. 349, pp. 510- 512 ,(1991) , 10.1038/349510A0
Emannuel Ramli, Thomas B. Rauchfuss, Charlotte L. Stern, Interception of copper polysulfide clusters in the reaction of copper and sulfur in donor solvents: polysulfide complexes as the link between molecular and nonmolecular metal sulfides Journal of the American Chemical Society. ,vol. 112, pp. 4043- 4044 ,(1990) , 10.1021/JA00166A054
Somanath. Dev, Emannuel. Ramli, Thomas B. Rauchfuss, Scott R. Wilson, Synthesis and structure of [M(N-methylimidazole)6]S8 (M = Mn, Fe, Ni, Mg). Polysulfide salts prepared by the reaction N-methylimidazole + metal powder + sulfur Inorganic Chemistry. ,vol. 30, pp. 2514- 2519 ,(1991) , 10.1021/IC00011A011
Deborah Murphy Wilhelmy, Egon Matijević, Preparation and properties of monodispersed spherical-colloidal particles of zinc sulphide Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. ,vol. 80, pp. 563- 570 ,(1984) , 10.1039/F19848000563
M. Polak, X-ray photoelectron spectroscopic studies of CdSe0.65 Te0.35 Journal of Electron Spectroscopy and Related Phenomena. ,vol. 28, pp. 171- 176 ,(1982) , 10.1016/0368-2048(82)85040-8
Y-M. Gao, P. Wu, J. Baglio, K. Dwight, A. Wold, Growth and characterization of zinc sulfide films by conversion of zinc oxide films with H2S Materials Research Bulletin. ,vol. 24, pp. 1215- 1221 ,(1989) , 10.1016/0025-5408(89)90196-7
G-Q. Yao, H-S. Shen, E.D. Honig, R. Kershaw, K. Dwight, A. Wold, Preparation and characterization of the quaternary chalcogenides Cu2B(II)C(IV)X4[B(II)=Zn, Cd; C(IV)=Si, Ge; X=S, Se] Solid State Ionics. ,vol. 24, pp. 249- 252 ,(1987) , 10.1016/0167-2738(87)90166-4
Atul K. Verma, Thomas B. Rauchfuss, Scott R. Wilson, Donor solvent mediated reactions of elemental zinc and sulfur, sans explosion Inorganic Chemistry. ,vol. 34, pp. 3072- 3078 ,(1995) , 10.1021/IC00115A038
Partha P. Paul, Thomas B. Rauchfuss, Scott R. Wilson, General synthesis of metalloid polysulfide complexes from the elements: structures of Sb2S152- and InS8(N-MeIm)- Journal of the American Chemical Society. ,vol. 115, pp. 3316- 3317 ,(1993) , 10.1021/JA00061A035