Effect of In–CNHC Bonds on the Synthesis, Structure, and Reactivity of Dialkylindium Alkoxides: How Indium Compares to Gallium
作者： Martyna Cybularczyk , Maciej Dranka , Janusz Zachara , Paweł Horeglad
DOI: 10.1021/ACS.ORGANOMET.6B00510
关键词: Medicinal chemistry 、 Adduct 、 Alkoxide 、 Organic chemistry 、 IMes 、 Alkyl 、 Alkoxy group 、 SIMes 、 Chemistry 、 Gallium 、 Reactivity (chemistry)
摘要: The investigation of the reactivity dialkylindium alkoxides toward N-heterocyclic carbenes (NHCs) has shown that both character In–CNHC bond and alkyl alkoxide substituents have a significant effect on formation R2InOR(NHC) complexes distribution products. reactions simple dimethylindium with 1,3-bis(2,4,6-trimethylphenyl)imidazolin-2-ylidene (SIMes) 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes) lead to monomeric Me2InOR(NHC), as by isolation Me2InOMe(NHC) (NHC = IMes (3), SIMes (4)). Compounds Me2InOR(NHC) are unstable in solution instantly disproportionate, which can be associated weaker comparison stable gallium analogues. As result, Me3In(NHC) (1), (2)) adducts, well Mitsubishi-type methylindium alkoxides, formed. exchange alkoxy group chelating (S)-methyl lactate (S-melac) resulted more s...
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sci-hub.se 参考文章(96)
Derek A. Tocher, Hywel O. Davies, Siama Basharat, Claire J. Carmalt, Sarah A. Barnett, Aerosol Assisted Chemical Vapor Deposition of In2O3Films from Me3In and Donor Functionalized Alcohols Inorganic Chemistry. ,vol. 46, pp. 9473- 9480 ,(2007) , 10.1021/IC701372B
Yang Yang, Haobing Wang, Haiyan Ma, Stereoselective Polymerization of rac-Lactide Catalyzed by Zinc Complexes with Tetradentate Aminophenolate Ligands in Different Coordination Patterns: Kinetics and Mechanism. Inorganic Chemistry. ,vol. 54, pp. 5839- 5854 ,(2015) , 10.1021/ACS.INORGCHEM.5B00558
Stanislaw Slomkowski, Stanislaw Penczek, Andrzej Duda, Polylactides—an overview Polymers for Advanced Technologies. ,vol. 25, pp. 436- 447 ,(2014) , 10.1002/PAT.3281
Manuel Kapitein, Carsten von Hänisch, None, Synthesis, Structures and Thermal Decomposition of Monomeric Aluminium, Gallium and Indium Silylphosphanides European Journal of Inorganic Chemistry. ,vol. 2015, pp. 837- 844 ,(2015) , 10.1002/EJIC.201402996
Caroline E. Knapp, Leah Pemberton, Claire J. Carmalt, David Pugh, Paul F. McMillan, Sarah A. Barnett, Derek A. Tocher, Synthesis, AACVD and X-ray crystallographic structures of group 13 monoalkoxometallanes Main Group Chemistry. ,vol. 9, pp. 31- 40 ,(2010) , 10.3233/MGC-2010-0002
D. C. Aluthge, J. M. Ahn, P. Mehrkhodavandi, Overcoming aggregation in indium salen catalysts for isoselective lactide polymerization Chemical Science. ,vol. 6, pp. 5284- 5292 ,(2015) , 10.1039/C5SC01584G
Wei Zhao, Yang Wang, Xinli Liu, Xuesi Chen, Dongmei Cui, Eugene Y.-X. Chen, Protic compound mediated living cross-chain-transfer polymerization of rac-lactide: synthesis of isotactic (crystalline)–heterotactic (amorphous) stereomultiblock polylactide Chemical Communications. ,vol. 48, pp. 6375- 6377 ,(2012) , 10.1039/C2CC32680A
Charles Romain, Lydia Brelot, Stéphane Bellemin-Laponnaz, Samuel Dagorne, Synthesis and Structural Characterization of a Novel Family of Titanium Complexes Bearing a Tridentate Bis-phenolate-N-heterocyclic Carbene Dianionic Ligand and Their Use in the Controlled ROP of rac-Lactide Organometallics. ,vol. 29, pp. 1191- 1198 ,(2010) , 10.1021/OM901084N
Adam J. Ruddy, Paul A. Rupar, Kamila J. Bladek, Christopher J. Allan, Jessica C. Avery, Kim M. Baines, On the Bonding in N-Heterocyclic Carbene Complexes of Germanium(II) Organometallics. ,vol. 29, pp. 1362- 1367 ,(2010) , 10.1021/OM900977G
Polly L. Arnold, Mark Rodden, Claire Wilson, Thermally stable potassium N-heterocyclic carbene complexes with alkoxide ligands, and a polymeric crystal structure with distorted, bridging carbenes Chemical Communications. pp. 1743- 1745 ,(2005) , 10.1039/B418302A