Preparation of thick mesoporous silica coating by electrophoretic deposition with binder addition and its water vapor adsorption–desorption properties

作者: Hideyuki Negishi , Ai Miyamoto , Akira Endo

DOI: 10.1016/J.MICROMESO.2013.06.040

关键词: DesiccantWater vaporMesoporous silicaThermal stabilityElectrophoretic depositionChromatographyHumidityChemical engineeringCoatingAdsorptionMaterials science

摘要: Abstract Ordered mesoporous silica (MPS) is expected to provide an adsorbent for energy-efficient air-conditioning systems, such as desiccant cooling humidity control and adsorption heat pumps, which can contribute the reduction of CO 2 emissions because they offer possibility recovery at temperatures low 50 °C. For these applications, it crucial establish a method fixing MPS on substrates with high thermal conductivity. We have already studied technological feasibility using electrophoretic deposition (EPD) process prepare thick coating powder metal substrate. In this study, we investigated EPD addition small amount binder succeeded in increasing mechanical strength stability coating. The approximately 100 μm-thick showed excellent water vapor adsorption–desorption properties sufficient more than 250 cycles, without any amount. dehumidification per cycle was 0.23 g-H O/g-MPS, correspond 6.9 g-H O/g-MPS/h.

参考文章(25)
Akira Endo, Yuki Inagi, Satoko Fujisaki, Takuji Yamamoto, Takao Ohmori, None, Synthesis of metal-doped mesoporous silica by spray drying and their adsorption properties of water vapor Studies in Surface Science and Catalysis. ,vol. 165, pp. 157- 160 ,(2007) , 10.1016/S0167-2991(07)80288-6
Alain Walcarius, Mesoporous materials and electrochemistry Chemical Society Reviews. ,vol. 42, pp. 4098- 4140 ,(2013) , 10.1039/C2CS35322A
A. Chavez-Valdez, M. S. P. Shaffer, A. R. Boccaccini, Applications of graphene electrophoretic deposition. A review Journal of Physical Chemistry B. ,vol. 117, pp. 1502- 1515 ,(2013) , 10.1021/JP3064917
Aldo R Boccaccini, Igor Zhitomirsky, Application of electrophoretic and electrolytic deposition techniques in ceramics processing Current Opinion in Solid State & Materials Science. ,vol. 6, pp. 251- 260 ,(2002) , 10.1016/S1359-0286(02)00080-3
Shigeo HAYASHI, Ryota KUSAMIZU, Fumito KAGAYA, Effects of different silica sol binders on properties of natural zeolite/silica sol deposits prepared by electrophoretic deposition Journal of the Ceramic Society of Japan. ,vol. 120, pp. 584- 588 ,(2012) , 10.2109/JCERSJ2.120.584
Katsuhiko Ariga, Ajayan Vinu, Yusuke Yamauchi, Qingmin Ji, Jonathan P. Hill, Nanoarchitectonics for mesoporous materials Bulletin of the Chemical Society of Japan. ,vol. 85, pp. 1- 32 ,(2012) , 10.1246/BCSJ.20110162
Saya Nakabayashi, Katsunori Nagano, Makoto Nakamura, Junya Togawa, Asami Kurokawa, Improvement of water vapor adsorption ability of natural mesoporous material by impregnating with chloride salts for development of a new desiccant filter Adsorption-journal of The International Adsorption Society. ,vol. 17, pp. 675- 686 ,(2011) , 10.1007/S10450-011-9363-1
Mitsuhiro Kubota, Takuya Hanada, Satoshi Yabe, Dalibor Kuchar, Hitoki Matsuda, Water desorption behavior of desiccant rotor under microwave irradiation Applied Thermal Engineering. ,vol. 31, pp. 1482- 1486 ,(2011) , 10.1016/J.APPLTHERMALENG.2011.01.027
Hideyuki Negishi, Akira Endo, Masaru Nakaiwa, Hiroshi Yanagishita, Preparation of Mesoporous Silicate Thick Films by Electrophoretic Deposition and Their Adsorption Properties of Water Vapor Key Engineering Materials. ,vol. 314, pp. 147- 152 ,(2006) , 10.4028/WWW.SCIENTIFIC.NET/KEM.314.147
T.S. Ge, Y.J. Dai, R.Z. Wang, Y. Li, Experimental investigation on a one-rotor two-stage rotary desiccant cooling system Energy. ,vol. 33, pp. 1807- 1815 ,(2008) , 10.1016/J.ENERGY.2008.08.006