Total Syntheses of Aflavazole and 14-Hydroxyaflavinine.
作者： Hailong Li , Qifeng Chen , Zhaohong Lu , Ang Li
DOI: 10.1021/JACS.6B10880
关键词: Molecule 、 Alkyne 、 Late stage 、 Allylic rearrangement 、 Olefin fiber 、 Prins reaction 、 Indole test 、 Chemistry 、 Stereochemistry 、 Steric effects
摘要: The first total syntheses of aflavazole (6) and 14-hydroxyaflavinine (8), two sterically congested indole diterpenoids, were accomplished. AlI3-promoted alkyne Prins cyclization …
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