Optical studies of cerium doped yttrium aluminum garnet single crystals

作者: C. M. Wong , S. R. Rotman , C. Warde

DOI: 10.1063/1.94629

关键词: Materials scienceYttriumCathodoluminescenceInorganic chemistryAnalytical chemistryLaserCrystallographic defectStimulated emissionAbsorption spectroscopyCeriumPhotoluminescence

摘要: Single crystals of undoped and cerium‐doped yttrium aluminum garnet have been pumped with laser radiation 220‐ 266‐nm wavelength. A broadband defect emission at approximately 300 nm was observed, similar to that obtained cathodoluminescence, although decreased in magnitude. Evidence a transfer energy from these states the Ce+3 inferred photoluminescence decay time measurements. We associated absorption spectra 200–300 excitation spectrum, including peaks 225 270 nm.

参考文章(18)
D. J. Robbins, B. Cockayne, J. L. Glasper, B. Lent, The Temperature Dependence of Rare‐Earth Activated Garnet Phosphors II . A Comparative Study of Ce3+, Eu3+, Tb3+, and Gd3+ in Journal of The Electrochemical Society. ,vol. 126, pp. 1221- 1228 ,(1979) , 10.1149/1.2129246
W. F. van der Weg, M. W. van Tol, Saturation effects of cathodoluminescence in rare‐earth activated epitaxial Y3Al5O12layers Applied Physics Letters. ,vol. 38, pp. 705- 707 ,(1981) , 10.1063/1.92486
James F. Owen, Paul B. Dorain, Takao Kobayasi, Excited‐state absorption in Eu+2: CaF2 and Ce+3: YAG single crystals at 298 and 77 K Journal of Applied Physics. ,vol. 52, pp. 1216- 1223 ,(1981) , 10.1063/1.329741
W. J. Miniscalco, J. M. Pellegrino, W. M. Yen, Measurements of excited‐state absorption in Ce3+ : YAG Journal of Applied Physics. ,vol. 49, pp. 6109- 6111 ,(1978) , 10.1063/1.324531
D. J. Robbins, B. Cockayne, B. Lent, J. L. Glasper, The Relationship Between Concentration and Efficiency in Rare Earth Activated Phosphors Journal of The Electrochemical Society. ,vol. 126, pp. 1556- 1563 ,(1979) , 10.1149/1.2129329
M.J. Weber, Nonradiative decay from 5d states of rare earths in crystals Solid State Communications. ,vol. 12, pp. 741- 744 ,(1973) , 10.1016/0038-1098(73)90326-8
Ralph R. Jacobs, William F. Krupke, Marvin J. Weber, Measurement of excited‐state‐absorption loss for Ce3+ in Y3Al5O12 and implications for tunable 5d→4f rare‐earth lasers Applied Physics Letters. ,vol. 33, pp. 410- 412 ,(1978) , 10.1063/1.90395
W. W. Holloway, M. Kestigian, Optical Properties of Cerium-Activated Garnet Crystals* Journal of the Optical Society of America. ,vol. 59, pp. 60- 63 ,(1969) , 10.1364/JOSA.59.000060
Glen A. Slack, D. W. Oliver, R. M. Chrenko, S. Roberts, Optical Absorption of Y 3 Al 5 O 12 from 10- to 55 000- cm − 1 Wave Numbers Physical Review. ,vol. 177, pp. 1308- 1314 ,(1969) , 10.1103/PHYSREV.177.1308