Structural, Dielectric, and Thermal Properties of Strontium Barium Niobate‐Doped Fused Silica Nanocomposites

作者: Sheng‐Guo Lu , Chee‐Leung Mak , Kin‐Hung Wong , None

DOI: 10.1111/J.1151-2916.2003.TB03472.X

关键词: DielectricFerroelectricityAnnealing (metallurgy)Raman spectroscopyBorosilicate glassDissipation factorAnalytical chemistryStrontium barium niobateMaterials scienceMineralogyDifferential thermal analysis

摘要: Ferroelectric strontium barium niobate (SBN)-doped Na2O–B2O3–SiO2 (NBS) glass nanocomposites were prepared by dispersing sol–gel-derived SBN powder into fused NBS glass. Their structures characterized X-ray diffractometry and Raman spectroscopy. The dielectric constants measured as functions of frequency temperature using an impedance analyzer. ferroelectric-to-paraelectric-phase transition was studied differential scanning calorimetric analysis. Our results revealed that the embedded has lower phase heat than those bulk materials. activation energy, however, is larger ultra-fine powders. Pure tetragonal-phase can be obtained at annealing temperatures 750°–1000°C. are ∼32–46 ∼20–25 low frequencies radio frequencies, respectively, loss tangent <0.1 room in range. studies suggested additional reduction properties must made before these systems considered for application microwave

参考文章(22)
K. WAKINO, K. MINAI, H. TAMURA, Microwave Characteristics of (Zr, Sn)TiO4 and BaO‐PbO‐Nd2O3‐TiO2 Dielectric Resonators Journal of the American Ceramic Society. ,vol. 67, pp. 278- 281 ,(2006) , 10.1111/J.1151-2916.1984.TB18847.X
Nicholas F. Borrelli, Margaret M. Layton, Dielectric and optical properties of transparent ferroelectric glass-ceramic systems Journal of Non-Crystalline Solids. ,vol. 6, pp. 197- 212 ,(1971) , 10.1016/0022-3093(71)90003-2
Daniel McCauley, Robert E. Newnham, Clive A. Randall, Intrinsic Size Effects in a Barium Titanate Glass-Ceramic Journal of the American Ceramic Society. ,vol. 81, pp. 979- 987 ,(2005) , 10.1111/J.1151-2916.1998.TB02435.X
K. C. Chen, A. Janah, J. D. Mackenzie, Crystallization Of Oxide Films Derived From Metallo-Organic Precursors MRS Proceedings. ,vol. 72, pp. 337- ,(1986) , 10.1557/PROC-72-337
Sheng‐Guo Lu, Chee‐Leung Mak, Kin‐Hung Wong, None, Low‐Temperature Preparation and Size Effect of Strontium Barium Niobate Ultrafine Powder Journal of the American Ceramic Society. ,vol. 84, pp. 79- 84 ,(2001) , 10.1111/J.1151-2916.2001.TB00611.X
T. Kokubo, M. Tashiro, Dielectric properties of fine-grained PbTiO3 crystals precipitated in a glass Journal of Non-crystalline Solids. ,vol. 13, pp. 328- 340 ,(1974) , 10.1016/0022-3093(74)90101-X
T. K. Kundu, D. Chakravorty, Nanocomposites of lead‐zirconate‐titanate glass ceramics and metallic silver Applied Physics Letters. ,vol. 67, pp. 2732- 2734 ,(1995) , 10.1063/1.114308