Roughness and fractality of nanostructured TiO2 films prepared via sol-gel technique
作者： P. Falaras , A. P. Xagas
关键词: Chemical engineering 、 Titanium dioxide 、 Nanocrystal 、 Mineralogy 、 Titanium isopropoxide 、 Surface finish 、 Materials science 、 Particle-size distribution 、 Sol-gel 、 Titanium 、 Nanostructure
摘要: Titanium dioxide nanocrystalline thin films were prepared by applying the sol-gel dipping technique using two different titanium (IV) alkoxides: isopropoxide and butoxide. Morphological, structural characterization examination of fractal properties performed atomic force microscopy (AFM). The effect nature precursor on hydrolysis rate resulting particle size distribution, roughness, surface complexity TiO2 was investigated. presents higher rates leading to more rough complex characteristics whereas butoxide show a relatively smoother surface. Higher dimension values lower roughness observed for titania derived from In both cases obtained present granular network interconnected particles, suitable practical applications.
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sci-hub.se 参考文章(20)
俊也 渡部, 和仁 橋本, 昭 藤嶋, TiO[2] photocatalysis : fundamentals and applications BKC. ,(1999)
Ezio Pelizzetti, Nick Serpone, Photocatalysis: Fundamentals and Applications ,(1989)
Ye Yonghong, Zhang Jiayu, Gu Peifu, Liu Xu, Tang Jinfa, Electrochromism of titanium oxide thin films Thin Solid Films. ,vol. 298, pp. 197- 199 ,(1997) , 10.1016/S0040-6090(96)08986-9
Petr Krtil, Ladislav Kavan, Dina Fattakhova, Insertion of lithium into mesoscopic anatase electrodes – an electrochemical and in-situ EQCM study Journal of Solid State Electrochemistry. ,vol. 1, pp. 83- 87 ,(1997) , 10.1007/S100080050026
Nilgun Ozer, Carl M. Lampert, Electrochromic characterization of sol-gel deposited coatings Solar Energy Materials and Solar Cells. ,vol. 54, pp. 147- 156 ,(1998) , 10.1016/S0927-0248(98)00065-8
Fei Cao, Gerko Oskam, Peter C. Searson, A Solid State, Dye Sensitized Photoelectrochemical Cell The Journal of Physical Chemistry. ,vol. 99, pp. 17071- 17073 ,(1995) , 10.1021/J100047A003
A.P. Xagas, E. Androulaki, A. Hiskia, P. Falaras, Preparation, fractal surface morphology and photocatalytic properties of TiO2 films Thin Solid Films. ,vol. 357, pp. 173- 178 ,(1999) , 10.1016/S0040-6090(99)00561-1
F. Babonneau, S. Doeuff, A. Leaustic, C. Sanchez, C. Cartier, M. Verdaguer, XANES and EXAFS study of titanium alkoxides Inorganic Chemistry. ,vol. 27, pp. 3166- 3172 ,(1988) , 10.1021/IC00291A024
Roberto Argazzi, Carlo A. Bignozzi, Todd A. Heimer, Felix N. Castellano, Gerald J. Meyer, Light-Induced Charge Separation across Ru(II)-Modified Nanocrystalline TiO2 Interfaces with Phenothiazine Donors Journal of Physical Chemistry B. ,vol. 101, pp. 2591- 2597 ,(1997) , 10.1021/JP9619393
O. Legrini, E. Oliveros, A. M. Braun, Photochemical processes for water treatment Chemical Reviews. ,vol. 93, pp. 671- 698 ,(1993) , 10.1021/CR00018A003