Self-Assembly in Poly(dimethylsiloxane)–Poly(ethylene oxide) Block Copolymer Template Directed Synthesis of Linde Type A Zeolite
作者： Lucio Bonaccorsi , Pietro Calandra , Mikhail A. Kiselev , Heinz Amenitsch , Edoardo Proverbio
DOI: 10.1021/LA400951S
关键词: Ethylene oxide 、 Amphiphile 、 Polymer chemistry 、 Hydrothermal synthesis 、 Small-angle X-ray scattering 、 Copolymer 、 Zeolite 、 Self-assembly 、 Materials science 、 Oxide
摘要: We describe the hydrothermal synthesis of zeolite Linde type A (LTA) submicrometer particles using a water-soluble amphiphilic block copolymer poly(dimethylsiloxane)-b-poly(ethylene oxide) as template. The formation and growth intermediate aggregates in presence diblock have been monitored by small-angle X-ray scattering (SAXS) above critical micellar concentration at constant temperature 45 °C. early stage process was characterized incorporation LTA components into surface with primary units 4.8 nm core–shell morphology. During this period, restricted to an initial time 1–3 h, structure does not show significant changes, while subsequent aggregation among these takes place. shape transition SAXS profile late has connected ...
acs.org
cheric.org
elsevier.com参考文章(31)
Stephan Förster, Markus Antonietti, Amphiphilic Block Copolymers in Structure-Controlled Nanomaterial Hybrids Advanced Materials. ,vol. 10, pp. 195- 217 ,(1998) , 10.1002/(SICI)1521-4095(199802)10:3<195::AID-ADMA195>3.0.CO;2-V
Lucio Bonaccorsi, Pietro Calandra, Heinz Amenitsch, Edoardo Proverbio, Domenico Lombardo, Growth of fractal aggregates during template directed SAPO-34 zeolite formation Microporous and Mesoporous Materials. ,vol. 167, pp. 3- 9 ,(2013) , 10.1016/J.MICROMESO.2012.10.024
Vladimir L. Zholobenko, Andrei Y. Khodakov, Marianne Impéror-Clerc, Dominique Durand, Isabelle Grillo, Initial stages of SBA-15 synthesis: An overview☆ Advances in Colloid and Interface Science. ,vol. 142, pp. 67- 74 ,(2008) , 10.1016/J.CIS.2008.05.003
H. Amenitsch, S. Bernstorff, M. Kriechbaum, D. Lombardo, H. Mio, M. Rappolt, P. Laggner, Performance and First Results of the ELETTRA High‐Flux Beamline for Small‐Angle X‐ray Scattering Journal of Applied Crystallography. ,vol. 30, pp. 872- 876 ,(1997) , 10.1107/S0021889897001593
Honghu Dai, Jintao Yang, Jingping Ma, Feng Chen, Zhengdong Fei, Mingqiang Zhong, A green process for the synthesis of controllable mesoporous silica materials Microporous and Mesoporous Materials. ,vol. 147, pp. 281- 285 ,(2012) , 10.1016/J.MICROMESO.2011.06.029
Kanghee Cho, Kyungsu Na, Jaeheon Kim, Osamu Terasaki, Ryong Ryoo, Zeolite Synthesis Using Hierarchical Structure-Directing Surfactants: Retaining Porous Structure of Initial Synthesis Gel and Precursors Chemistry of Materials. ,vol. 24, pp. 2733- 2738 ,(2012) , 10.1021/CM300841V
Yingjie Jin, Yongdan Li, Haiyan Wang, Shanlin Zhao, Zhenbo Lv, Xiamei Du, Yueqiao Sun, Textural mesoporosity and opening frame network of mesoporous MOR zeolites synthesized under intensifying perturbation conditions Microporous and Mesoporous Materials. ,vol. 153, pp. 144- 154 ,(2012) , 10.1016/J.MICROMESO.2011.12.038
Luigi Pasqua, Flaviano Testa, Rosario Aiello, Sante Cundari, Janos B. Nagy, Preparation of bifunctional hybrid mesoporous silica potentially useful for drug targeting Microporous and Mesoporous Materials. ,vol. 103, pp. 166- 173 ,(2007) , 10.1016/J.MICROMESO.2007.01.045
Somnath Ghosh, A. Saraswathi, S. S. Indi, S. L. Hoti, H. N. Vasan, Ag@AgI, Core@Shell Structure in Agarose Matrix as Hybrid: Synthesis, Characterization, and Antimicrobial Activity Langmuir. ,vol. 28, pp. 8550- 8561 ,(2012) , 10.1021/LA301322J
Domenico Lombardo, Norberto Micali, Valentina Villari, Mikhail A. Kiselev, Large structures in diblock copolymer micellar solution. Physical Review E. ,vol. 70, pp. 021402- 021402 ,(2004) , 10.1103/PHYSREVE.70.021402