Layer-by-layer structured films of TiO2 nanoparticles and poly(acrylic acid) on electrospun nanofibres
作者： Bin Ding , Jinho Kim , Eiji Kimura , Seimei Shiratori
DOI: 10.1088/0957-4484/15/8/007
关键词: BET theory 、 Scanning electron microscope 、 Composite material 、 Anatase 、 Layer by layer 、 Acrylic acid 、 Cellulose acetate 、 Materials science 、 Transmission electron microscopy 、 Fourier transform infrared spectroscopy
摘要: We report a new approach for fabricating layer-by-layer (LBL) structured ultrathin hybrid films on electrospun nanofibres. Oppositely charged anatase TiO2 nanoparticles and poly(acrylic acid) (PAA) were alternately deposited the surface of negatively cellulose acetate (CA) nanofibres using electrostatic LBL self-assembly technique. The fibrous mats characterized by wide-angle x-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, transmission microscopy Brunauer–Emmett–Teller (BET) area techniques. crystalline phase remained unchanged in resultant TiO2/PAA coated CA mats. Moreover, film fibres showed rough surfaces with grains due to deposition aggregated particles. average diameter increased from 344 584 nm BET 2.5 6.0 m2 g−1 after coating five bilayers films.
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sci-hub.se 参考文章(32)
Tran Trung, Chang-Sik Ha, One-component solution system to prepare nanometric anatase TiO2 Materials Science and Engineering: C. ,vol. 24, pp. 19- 22 ,(2004) , 10.1016/J.MSEC.2003.09.004
P. Murugavel, M. Kalaiselvam, A. R. Raju, C. N. R. Rao, Sub-micrometre spherical particles of TiO2, ZrO2, and PZT by nebulized spray pyrolysis of metal-organic precursors Journal of Materials Chemistry. ,vol. 7, pp. 1433- 1438 ,(1997) , 10.1039/A700301C
Bin Ding, Eiji Kimura, Tomokazu Sato, Shiro Fujita, Seimei Shiratori, Fabrication of blend biodegradable nanofibrous nonwoven mats via multi-jet electrospinning Polymer. ,vol. 45, pp. 1895- 1902 ,(2004) , 10.1016/J.POLYMER.2004.01.026
Tien-Syh Yang, Ching-Bin Shiu, Ming-Show Wong, Structure and hydrophilicity of titanium oxide films prepared by electron beam evaporation Surface Science. ,vol. 548, pp. 75- 82 ,(2004) , 10.1016/J.SUSC.2003.10.044
H Lin, H Kozuka, T Yoko, Preparation of TiO2 films on self-assembled monolayers by sol–gel method Thin Solid Films. ,vol. 315, pp. 111- 117 ,(1998) , 10.1016/S0040-6090(97)00759-1
Christopher Drew, Xin Liu, David Ziegler, Xianyan Wang, Ferdinando F. Bruno, James Whitten, Lynne A. Samuelson, Jayant Kumar, Metal Oxide-Coated Polymer Nanofibers Nano Letters. ,vol. 3, pp. 143- 147 ,(2003) , 10.1021/NL025850M
H Fong, I Chun, D.H Reneker, Beaded nanofibers formed during electrospinning Polymer. ,vol. 40, pp. 4585- 4592 ,(1999) , 10.1016/S0032-3861(99)00068-3
R. A. Caruso, J. H. Schattka, A. Greiner, Titanium dioxide tubes from sol-gel coating of electrospun polymer fibers. Advanced Materials. ,vol. 13, pp. 1577- 1579 ,(2001) , 10.1002/1521-4095(200110)13:20<1577::AID-ADMA1577>3.0.CO;2-S
M. Todd Crisp, Nicholas A. Kotov, Preparation of nanoparticle coatings on surfaces of complex geometry Nano Letters. ,vol. 3, pp. 173- 177 ,(2003) , 10.1021/NL025896F
Hiroaki Tokuhisa, Paula T. Hammond, Nonlithographic micro- and nanopatterning of TiO2 using polymer stamped molecular templates. Langmuir. ,vol. 20, pp. 1436- 1441 ,(2004) , 10.1021/LA030191U