Offgas analysis and pyrolysis mechanism of activated carbon from bamboo sawdust by chemical activation with KOH
作者： Yong Tian , Ping Liu , Xiufang Wang , Guoying Zhong , Guanke Chen
DOI: 10.1007/S11595-011-0157-9
关键词: Composite material 、 Gas analyzer 、 Sawdust 、 Activated carbon 、 Bamboo 、 Induction period 、 Pyrolytic carbon 、 Thermogravimetric analysis 、 Chemistry 、 Chemical engineering 、 Pyrolysis
摘要: Bamboo sawdust was used as the precursor for multipurpose use of waste. Offgases released during activation process bamboo by KOH were investigated quantitatively and qualitatively a gas analyzer. TG/DTG curves pyrolysis with different impregnation weight ratios (KOH to bamboo) obtained thermogravimetric Pyrolysis mechanism proposed. The results showed that offgases composed CO, NO, SO2 hydrocarbon concentration 1 372, 37, 86, 215 mg/L, respectively. Thermogravimetric analysis indicated pyrolytic mainly experienced two steps. first low temperature step (lower than 300°C), which pre-activation induction period. second high step(higher 550°C), radial followed pore production. key control distribution final product.
springer.com
cnki.com.cn参考文章(12)
D. A. Cadenhead, D. M. Rosenberg, James Frederic Danielli, Progress in surface and membrane science Academic Press. ,(1971)
Luis M. Cotoruelo, María D. Marqués, José Rodríguez-Mirasol, Juan J. Rodríguez, Tomás Cordero, Lignin-based activated carbons for adsorption of sodium dodecylbenzene sulfonate: Equilibrium and kinetic studies. Journal of Colloid and Interface Science. ,vol. 332, pp. 39- 45 ,(2009) , 10.1016/J.JCIS.2008.12.031
Aik Chong Lua, Ting Yang, Jia Guo, Effects of pyrolysis conditions on the properties of activated carbons prepared from pistachio-nut shells Journal of Analytical and Applied Pyrolysis. ,vol. 72, pp. 279- 287 ,(2004) , 10.1016/J.JAAP.2004.08.001
R. Aravindhan, J. Raghava Rao, B. Unni Nair, Preparation and characterization of activated carbon from marine macro-algal biomass Journal of Hazardous Materials. ,vol. 162, pp. 688- 694 ,(2009) , 10.1016/J.JHAZMAT.2008.05.083
D.D. Do, S. Junpirom, H.D. Do, A new adsorption–desorption model for water adsorption in activated carbon Carbon. ,vol. 47, pp. 1466- 1473 ,(2009) , 10.1016/J.CARBON.2009.01.039
P.J.M. Carrott, M.M.L. Ribeiro Carrott, P.A.M. Mourão, Pore size control in activated carbons obtained by pyrolysis under different conditions of chemically impregnated cork Journal of Analytical and Applied Pyrolysis. ,vol. 75, pp. 120- 127 ,(2006) , 10.1016/J.JAAP.2005.04.013
A. Linares-Solano, C. Salinas-Martínez de Lecea, D. Cazorla-Amorós, I. Martín-Gullón, Porosity Development during CO2 and Steam Activation in a Fluidized Bed Reactor Energy & Fuels. ,vol. 14, pp. 142- 149 ,(2000) , 10.1021/EF9900637
Satoshi Mitani, Sang-Ick Lee, Koji Saito, Seong-Ho Yoon, Yozo Korai, Isao Mochida, Activation of coal tar derived needle coke with K2CO3 into an active carbon of low surface area and its performance as unique electrode of electric double-layer capacitor Carbon. ,vol. 43, pp. 2960- 2967 ,(2005) , 10.1016/J.CARBON.2005.05.047
W Xing, SZ Qiao, RG Ding, F Li, GQ Lu, ZF Yan, HM Cheng, None, Superior electric double layer capacitors using ordered mesoporous carbons Carbon. ,vol. 44, pp. 216- 224 ,(2006) , 10.1016/J.CARBON.2005.07.029
Keith K.H. Choy, John P. Barford, Gordon McKay, Production of activated carbon from bamboo scaffolding waste—process design, evaluation and sensitivity analysis Chemical Engineering Journal. ,vol. 109, pp. 147- 165 ,(2005) , 10.1016/J.CEJ.2005.02.030