Development of a conjugated polyaniline incorporated electrospun poly(vinylidene fluoride‐co‐hexafluoropropylene) composite membrane electrolyte for high performance dye‐sensitized solar cells
作者： Vijayakumar Elayappan , Vignesh Murugadoss , Subramania Angaiah , Zhaofu Fei , Paul J. Dyson
DOI: 10.1002/APP.42777
关键词: Materials science 、 Polyaniline 、 Polymer chemistry 、 Chemical engineering 、 Tafel equation 、 Polarization (electrochemistry) 、 Membrane 、 Hexafluoropropylene 、 Crystallinity 、 Dye-sensitized solar cell 、 Electrolyte
摘要: Different weight percentage (2, 3, 4, and 5 wt %) of polyaniline (PANI) were incorporated into electrospun poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP) composite membranes (esCPMs). The regular morphology, molecular structure, crystallinity, porosity, electrolyte uptake, leakage the examined. esCPMs activated in liquid containing 0.5 M LiI, 0.05 I-2, 4-tert-butylpyridine 1-butyl-3-methylimidazoliun iodide acetonitrile to afford PVdF-HFP/PANI membrane electrolytes (esCPMEs). influence different % PANI on esCPMEs was studied by electrochemical impedance measurements Tafel polarization studies. photovoltaic performance a dye-sensitized solar cell assembled using 3 esCPME exhibits higher power conversion efficiency 7.20% than that esPME (=6.42%).
core.ac.uk
sci-hub.se 参考文章(40)
Ruobing Han, Shan Lu, Yanjie Wang, Xuehua Zhang, Qiang Wu, Tao He, Influence of monomer concentration during polymerization on performance and catalytic mechanism of resultant poly(3,4-ethylenedioxythiophene) counter electrodes for dye-sensitized solar cells Electrochimica Acta. ,vol. 173, pp. 796- 803 ,(2015) , 10.1016/J.ELECTACTA.2015.05.130
E. Vijayakumar, A. Subramania, Zhaofu Fei, Paul J. Dyson, High-performance dye-sensitized solar cell based on an electrospun poly(vinylidene fluoride-co-hexafluoropropylene)/cobalt sulfide nanocomposite membrane electrolyte RSC Advances. ,vol. 5, pp. 52026- 52032 ,(2015) , 10.1039/C5RA04944J
Ji-Un Kim, Sung-Hae Park, Hyong-Ju Choi, Won-Ki Lee, Jin-Kook Lee, Mi-Ra Kim, Effect of electrolyte in electrospun poly(vinylidene fluoride-co-hexafluoropropylene) nanofibers on dye-sensitized solar cells Solar Energy Materials and Solar Cells. ,vol. 93, pp. 803- 807 ,(2009) , 10.1016/J.SOLMAT.2008.09.045
Jihuai Wu, Zhang Lan, Jianming Lin, Miaoliang Huang, Yunfang Huang, Leqing Fan, Genggeng Luo, Electrolytes in Dye-Sensitized Solar Cells Chemical Reviews. ,vol. 115, pp. 2136- 2173 ,(2015) , 10.1021/CR400675M
Mohamad Ayad, Gad El-Hefnawy, Sawsan Zaghlol, Facile synthesis of polyaniline nanoparticles; its adsorption behavior Chemical Engineering Journal. ,vol. 217, pp. 460- 465 ,(2013) , 10.1016/J.CEJ.2012.11.099
Brian O'Regan, Michael Grätzel, A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films Nature. ,vol. 353, pp. 737- 740 ,(1991) , 10.1038/353737A0
Marcela A. Bavio, Gerardo G. Acosta, Teresita Kessler, Synthesis and characterization of polyaniline and polyaniline – Carbon nanotubes nanostructures for electrochemical supercapacitors Journal of Power Sources. ,vol. 245, pp. 475- 481 ,(2014) , 10.1016/J.JPOWSOUR.2013.06.119
Yanyan Duan, Qunwei Tang, Yuran Chen, Zhiyuan Zhao, Yang Lv, Mengjin Hou, Peizhi Yang, Benlin He, Liangmin Yu, Solid-state dye-sensitized solar cells from poly(ethylene oxide)/polyaniline electrolytes with catalytic and hole-transporting characteristics Journal of Materials Chemistry. ,vol. 3, pp. 5368- 5374 ,(2015) , 10.1039/C4TA06393G
J Bandara, J P Yasomanee, p-type oxide semiconductors as hole collectors in dye-sensitized solid-state solar cells Semiconductor Science and Technology. ,vol. 22, pp. 20- 24 ,(2007) , 10.1088/0268-1242/22/2/004
Varishetty Madhu Mohan, Kenji Murakami, Akinori Kono, Masaru Shimomura, Poly(acrylonitrile)/activated carbon composite polymer gel electrolyte for high efficiency dye sensitized solar cells Journal of Materials Chemistry. ,vol. 1, pp. 7399- 7407 ,(2013) , 10.1039/C3TA10392G