Dimensional stability and electrochemical behaviour of ZrO2 incorporated electrospun PVdF-HFP based nanocomposite polymer membrane electrolyte for Li-ion capacitors.
作者： Arun Kumar Solarajan , Vignesh Murugadoss , Subramania Angaiah
DOI: 10.1038/SREP45390
关键词:
摘要: Different weight percentages of ZrO2 (0, 3, 5, 7 and 10 wt%) incorporated electrospun PVDF-HFP nanocomposite polymer membranes (esCPMs) were prepared by electrospinning technique. They activated soaking in 1 M LiPF6 containing 1:1 volume ratio EC : DMC (ethylene carbonate:dimethyl carbonate) to get membrane electrolytes (esCPMEs). The influence on the physical, mechanical electrochemical properties esCPM was studied detail. Finally, coin type Li-ion capacitor cell assembled using LiCo0.2Mn1.8O4 as cathode, Activated carbon anode esCPME 7 wt% separator, which delivered a discharge capacitance 182.5 Fg-1 at current density 1Ag-1 retained 92% its initial even after 2,000 cycles. It revealed that PVdF-HFP/ZrO2 based electrolyte could be used good candidate for high performance capacitors.
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springer.com 参考文章(22)
Vijayakumar Elayappan, Vignesh Murugadoss, Subramania Angaiah, Zhaofu Fei, Paul J. Dyson, Development of a conjugated polyaniline incorporated electrospun poly(vinylidene fluoride‐co‐hexafluoropropylene) composite membrane electrolyte for high performance dye‐sensitized solar cells Journal of Applied Polymer Science. ,vol. 132, pp. 42777- ,(2015) , 10.1002/APP.42777
Ke Xiao, Yunyun Zhai, Jianyong Yu, Bin Ding, Nanonet-structured poly(m-phenylene isophthalamide)─polyurethane membranes with enhanced thermostability and wettability for high power lithium ion batteries RSC Advances. ,vol. 5, pp. 55478- 55485 ,(2015) , 10.1039/C5RA09325B
Hong-Ryun Jung, Dong-Hyuk Ju, Wan-Jin Lee, Xiangwu Zhang, Richard Kotek, Electrospun hydrophilic fumed silica/polyacrylonitrile nanofiber-based composite electrolyte membranes Electrochimica Acta. ,vol. 54, pp. 3630- 3637 ,(2009) , 10.1016/J.ELECTACTA.2009.01.039
Chen Shen, Jianming Wang, Zheng Tang, Huijuan Wang, Huiqin Lian, Jianqing Zhang, Chu-nan Cao, Physicochemical properties of poly(ethylene oxide)-based composite polymer electrolytes with a silane-modified mesoporous silica SBA-15 Electrochimica Acta. ,vol. 54, pp. 3490- 3494 ,(2009) , 10.1016/J.ELECTACTA.2009.01.014
Shiro Seki, Md. Abu Bin Hasan Susan, Taketo Kaneko, Hiroyuki Tokuda, Akihiro Noda, Masayoshi Watanabe, Distinct difference in ionic transport behavior in polymer electrolytes depending on the matrix polymers and incorporated salts Journal of Physical Chemistry B. ,vol. 109, pp. 3886- 3892 ,(2005) , 10.1021/JP045328J
Lee T. K., A. Ahmad, N. Hasyareeda, Preparation and Characterization on Nano-hybrid Composite Solid Polymer Electrolyte of PVdF-HFP /MG49- ZrO 2 for Battery Application THE 2014 UKM FST POSTGRADUATE COLLOQUIUM: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2014 Postgraduate Colloquium. ,vol. 1614, pp. 404- 409 ,(2014) , 10.1063/1.4895231
F. Croce, L. Settimi, B. Scrosati, Superacid ZrO2-added, composite polymer electrolytes with improved transport properties Electrochemistry Communications. ,vol. 8, pp. 364- 368 ,(2006) , 10.1016/J.ELECOM.2005.12.002
V. Aravindan, P. Vickraman, T. Prem Kumar, ZrO2 nanofiller incorporated PVC/PVdF blend-based composite polymer electrolytes (CPE) complexed with LiBOB Journal of Membrane Science. ,vol. 305, pp. 146- 151 ,(2007) , 10.1016/J.MEMSCI.2007.07.044
S. Rajendran, T. Uma, T. Mahalingam, Effect of ZrO2 on the conductivity of PVC-LiAsF6-DBP polymer electrolytes Ionics. ,vol. 5, pp. 227- 231 ,(1999) , 10.1007/BF02375844
Iresha R. M. Kottegoda, Zhumabay Bakenov, Hiromasa Ikuta, Masataka Wakihara, Stability of Lithium Polymer Battery Based on Substituted Spinel Cathode and PEG-Borate Ester∕PC Plasticized Polymer Electrolyte Journal of The Electrochemical Society. ,vol. 152, ,(2005) , 10.1149/1.1946387