Solid phase extraction of uranium on a new brush type graft copolymer and spectrophotometric determination of its in water samples
作者： Mustafa Tuzen , Esra Bagda , Baki Hazer
DOI: 10.1007/S10967-016-4949-4
关键词: Solid phase extraction 、 Adsorption 、 Analytical chemistry 、 Methacrylate 、 Nuclear chemistry 、 Chemistry 、 Uranium 、 Copolymer 、 Detection limit 、 Polymer 、 Amphiphile
摘要: A new versatile solid phase extraction and spectrophotometric determination of uranium (VI) was proposed with using poly(caprolactone-b-vinyl benzyl chloride-g-dimethyl amino ethyl methacrylate), poly(CL-b-VB-g-DMAEMA), amphiphilic brush type block/graft copolymer. The method is based on the adsorption uranium(VI)-pyrocatechol violet complex surface adsorbent. parameters such as pH, amount ligand copolymer, sample volume were optimized. Detection limit, preconcentration factor relative standard deviation found 0.45 µg L−1, 100 3.8 %, respectively. Adsorption capacity polymer for uranium(VI) 52 mg g−1. applied to different water samples reference materials.
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Xin Liu, Tiancheng Wang, Jingru Li, Jue Cheng, Junying Zhang, Synthesis and properties of segmented polyurethanes with hydroquinone ether derivatives as chain extender Journal of Polymer Research. ,vol. 22, pp. 1- 11 ,(2015) , 10.1007/S10965-015-0792-5
Hua-Zi Huang, Chan Il Park, Gi Won Cha, Spectrophotometric Determination of Uranium(VI)with Pyrocatechol Violet in Surfactant Media Bulletin of The Korean Chemical Society. ,vol. 22, pp. 84- 86 ,(2001)
P. D. B. Sonali, K. Ajay, J. R. Priyanka, K. Rupali, V. K. Rajesh, S. Rajvir, K. S. Pradeepkumar, Comparison of radiometric and non-radiometric methods for uranium determination in groundwater of Punjab, India Journal of Radioanalytical and Nuclear Chemistry. ,vol. 307, pp. 395- 405 ,(2016) , 10.1007/S10967-015-4132-3
Ayla Campos do Lago, Grazielle Cabral de Lima, Célio Wisniewski, Marcos Roberto Lopes do Nascimento, Pedro Sergio Fadini, Pedro Orival Luccas, Determination of Uranium in Environmental Water by Flow Injection Analysis using a Hybrid-Imprinted Polymer Analytical Letters. ,vol. 48, pp. 2739- 2753 ,(2015) , 10.1080/00032719.2015.1046550
R. V. Subba Rao, K. Damodaran, G. Santosh Kumar, T. N. Ravi, Determination of Uranium and Plutonium in High Active Solutions by Extractive Spectrophotometry Journal of Radioanalytical and Nuclear Chemistry. ,vol. 246, pp. 433- 435 ,(2000) , 10.1023/A:1006788321971
S. Sadeghi, E. Sheikhzadeh, Solid phase extraction using silica gel modified with murexide for preconcentration of uranium (VI) ions from water samples. Journal of Hazardous Materials. ,vol. 163, pp. 861- 868 ,(2009) , 10.1016/J.JHAZMAT.2008.07.053
S. Panja, P.K. Mohapatra, S.C. Tripathi, P.M. Gandhi, P. Janardan, A highly efficient solvent system containing TODGA in room temperature ionic liquids for actinide extraction Separation and Purification Technology. ,vol. 96, pp. 289- 295 ,(2012) , 10.1016/J.SEPPUR.2012.06.015
Mohammad Rezaee, Faezeh Khalilian, Determination of uranium in water samples using homogeneous liquid–liquid microextraction via flotation assistance and inductively coupled plasma-optical emission spectrometry Journal of Radioanalytical and Nuclear Chemistry. ,vol. 304, pp. 1193- 1200 ,(2015) , 10.1007/S10967-015-3951-6
C. A. Moody, S. E. Glover, D. B. Stuit, R. H. Filby, Pre-concentration and separation of thorium, uranium, plutonium and americium in human soft tissues by extraction chromatography Journal of Radioanalytical and Nuclear Chemistry. ,vol. 234, pp. 183- 188 ,(1998) , 10.1007/BF02389769
B. Danko, R. Dybczyński, Determination of molybdenum and uranium in biological materials by radiochemical neutron activation analysis Journal of Radioanalytical and Nuclear Chemistry. ,vol. 216, pp. 51- 57 ,(1997) , 10.1007/BF02034495