Discreteness‐of‐charge‐effects in the inner region of the electrical double layer

摘要: The effects of the discreteness adsorbed ionic charge in electrical double layer have been examined. formula Esin and Shikov [2] for ratio micropotential to macropotential has confirmed. In agreement with Ershler [3] it is concluded that if one neglects multiple reflection ions between outer Helmholtz plane metallic surface, a contradiction experiment appears. Taking these into account shown potential developed by two reflecting planes, or air plane, just half what would compute no planes were present place first real charges at image positions solution. rate change electro-capillary maximum respect activity an electrolyte reexamined extended include charged as well uncharged surfaces. An adsorption isotherm anions on airsolution interface derived methods found evaluation inner plane.