A new type of insulated molecular wire: a rotaxane derived from a metal-capped conjugated tetrayne
作者： Nancy Weisbach , Zuzana Baranová , Sébastien Gauthier , Joseph H. Reibenspies , John A. Gladysz
DOI: 10.1039/C2CC33321J
关键词: Polymer chemistry 、 Conjugated system 、 Rotaxane 、 Crystal structure 、 Carbon chain 、 Adduct 、 Chemistry 、 Platinum 、 Stereochemistry 、 Molecular wire
摘要: The platinum butadiynyl complex trans-(C(6)F(5))(p-tol(3)P)(2)Pt(C≡C)(2)H and a CuI adduct of 1,10-phenanthroline based 33-membered macrocycle react in the presence K(2)CO(3) I(2) or O(2) to give rotaxane (ca. 9%) which is threaded by sp carbon chain trans,trans-(C(6)F(5))(p-tol(3)P)(2)Pt(C≡C)(4)Pt(Pp-tol(3))(2)(C(6)F(5)). crystal structure macrocycle/axle electronic interactions are analyzed detail.
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