Molar volumes of Al, Li, Mg and Si

作者: Bengt Hallstedt

DOI: 10.1016/J.CALPHAD.2006.10.006

关键词: DiamondLattice constantMineralogySolid solutionAnalytical chemistryMolar volumePolynomial ExpressionMolarChemistry

摘要: The molar volumes of the fcc, bcc, hcp and liquid phases Al, Li, Mg Si as well diamond have been evaluated functions temperature based on experimental data from literature. volume each element in structure is described by a single polynomial expression function temperature. These polynomials can be used above around 150 K. liquids were linear dependence. nonstable structures with help lattice parameter measurements corresponding solid solutions. A large majority solutions studied showed negative excess volumes. relatively closely packed bcc always found to very close other, reasonably good approximation would set them equal.

参考文章(113)
Hiromichi Watanabe, N. Yamada, M. Okaji, Development of a Laser Interferometric Dilatometer for Measurements of Thermal Expansion of Solids in the Temperature Range 300 to 1300 K International Journal of Thermophysics. ,vol. 23, pp. 543- 554 ,(2002) , 10.1023/A:1015117704933
G. Borelius, Changes of State of Simple Solid and Liquid Metals Advances in Research and Applications. ,vol. 6, pp. 65- 94 ,(1958) , 10.1016/S0081-1947(08)60725-0
Roland W. Ohse, Handbook of thermodynamic and transport properties of alkali metals Blackwell Scientific. ,(1985)
William Paul, Douglas M. Warschauer, Solids under pressure McGraw-Hill. ,(1963)
S.C. Agarwal, M.J. Koczak, H. Herman, Precipitation in liquid-quenched Al-base Si Scripta Metallurgica. ,vol. 7, pp. 365- 370 ,(1973) , 10.1016/0036-9748(73)90057-4
A. Kochanovska, Investigation of thermal dilatation of cubic metals Physica D: Nonlinear Phenomena. ,vol. 15, pp. 191- 196 ,(1949) , 10.1016/0031-8914(49)90043-9
R B Roberts, Thermal expansion reference data: silicon 300-850 K Journal of Physics D. ,vol. 14, ,(1981) , 10.1088/0022-3727/14/10/003
F. R. Kroeger, C. A. Swenson, Absolute linear thermal‐expansion measurements on copper and aluminum from 5 to 320 K Journal of Applied Physics. ,vol. 48, pp. 853- 864 ,(1977) , 10.1063/1.323746