作者: Nejc Hodnik , Claudio Baldizzone , George Polymeros , Simon Geiger , Jan-Philipp Grote
DOI: 10.1038/NCOMMS13164
关键词: Chemical engineering 、 Platinum 、 Metal 、 Electrocatalyst 、 Aqua regia 、 Industrial catalysts 、 Materials science 、 Corrosion 、 Reagent 、 Dissolution
摘要: The recycling of precious metals, for example, platinum, is an essential aspect sustainability the modern industry and energy sectors. However, due to its resistance corrosion, platinum-leaching techniques rely on high reagent consumption hazardous processes, boiling aqua regia; a mixture concentrated nitric hydrochloric acid. Here we demonstrate that complete dissolution metallic platinum can be achieved by induced surface potential alteration, ‘electrode-less’ process utilizing alternatively oxidative reductive gases. This concept exploits so-called transient mechanism, triggered repetitive change in oxidation state, without using any external electric current or electrodes. effective performance non-toxic low-concentrated acid at room temperature strong benefit this approach, potentially rendering industrial catalysts, including but not limited platinum-based systems, more sustainable. Given scarcity cost it important develop sustainable processes recycling. Here, authors report gases repetitively absence current.