Influence of Substituents, Reaction Conditions and Central Metals on the Isomer Distributions of 1(4)-Tetrasubstituted Phthalocyanines
作者： Christine Rager , Gabriele Schmid , Michael Hanack
DOI: 10.1002/(SICI)1521-3765(19990104)5:1<280::AID-CHEM280>3.0.CO;2-0
关键词: Chirality (chemistry) 、 Stereochemistry 、 Reaction conditions 、 Structural isomer 、 Chemistry 、 Medicinal chemistry 、 General chemistry
摘要: Several 1(4)- and 2(3)-tetraalkoxy-substituted phthalocyanines (shown) were synthesized from the corresponding (R,S)-, (R)-, (S)- alkoxy-substituted phthalonitriles, four structural isomers formed for each separated by HPLC. The influence of (S)-substituents on isomer distribution is discussed. M = Cu, Ni, Zn.
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