Synthesis and spectral properties of soluble trimethylsilyl substituted metal-phthalocyanines

作者: L Guo , F.S Meng , X.D Gong , H.M Xiao , K.C Chen

DOI: 10.1016/S0143-7208(01)00011-0

关键词:

摘要: Abstract By in situ trapping of lithiated phthalocyanines with chlorotrimethylsilane, several highly soluble trimethylsilyl non-peripherally substituted were synthesized. The photodegradation the resultant ZnPcs different organic solvents was found to follow quasi-first order kinetics and degradation products determined aid GC–MS. A mechanism for process has been proposed is supported by results from MO calculations.

参考文章(13)
Wolfgang Rettig, Bernd Strehmel, Sigurd Schrader, Holger Seifert, Applied Fluorescence in Chemistry, Biology and Medicine Springer Berlin Heidelberg. ,(1999) , 10.1007/978-3-642-59903-3
Wu Yongzhong, Tian He, Chen Kongchang, Liu Yunqi, Zhu Daoben, Synthesis and properties of soluble metal-free phthalocyanines containing tetra- or octa-alkyloxy substituents Dyes and Pigments. ,vol. 37, pp. 317- 325 ,(1998) , 10.1016/S0143-7208(97)00070-3
Josef Metz, Otto Schneider, Michael Hanack, Synthesis and properties of substituted (phthalocyaninato)-iron and -cobalt compounds and their pyridine adducts Inorganic Chemistry. ,vol. 23, pp. 1065- 1071 ,(1984) , 10.1021/IC00176A014
M. J. Chen, C. M. Fendrick, R. A. Watson, K. S. Kinter, J. W. Rathke, Regiospecific ortho-lithiation of phthalocyanines: a route for one-step synthesis of highly soluble trimethylsilyl substituted phthalocyanines Journal of The Chemical Society-perkin Transactions 1. pp. 1071- 1073 ,(1989) , 10.1039/P19890001071
Nagao Kobayashi, Yoshiyuki Nishiyama, A copper phthalocyanine with four crown ether voids Journal of The Chemical Society, Chemical Communications. pp. 1462- 1463 ,(1986) , 10.1039/C39860001462
Clifford C. Leznoff, Shafrira Greenberg, Ben Khouw, A. B. P. Lever, The syntheses of mono- and disubstituted phthalocyanines using a dithioimide Canadian Journal of Chemistry. ,vol. 65, pp. 1705- 1713 ,(1987) , 10.1139/V87-285
Ali R. Koray, Vefa Ahsen, Özer Bekâroǧlu, Preparation of a novel, soluble copper phthalocyanine with crown ether moieties Journal of The Chemical Society, Chemical Communications. pp. 932- 933 ,(1986) , 10.1039/C39860000932
Garry C. Whitelam, Alex C. McCormac, Margaret T. Boylan, Peter H. Quail, Photoresponses of Arabidopsis seedlings expressing an introduced oat phyA cDNA : persistence of etiolated plant type responses in light-grown plants Photochemistry and Photobiology. ,vol. 56, pp. 617- 621 ,(1992) , 10.1111/J.1751-1097.1992.TB02211.X