Peripherally alpha(α)-substituted novel phthalocyanines
作者： Mahmut Durmuş , Mehmet Menaf Ayhan , Ayşe Gül Gürek , Vefa Ahsen
DOI: 10.1016/J.DYEPIG.2007.08.010
关键词: Phthalocyanine 、 Medicinal chemistry 、 Alpha (ethology) 、 Nickel 、 Alkoxy group 、 Nickel phthalocyanine 、 Chemistry 、 Chloroform 、 Photochemistry
摘要: Abstract Two novel, nickel phthalocyanines bearing peripherally alpha(α)-substituents, namely octa(1,3-bis(dodecyloxy)propan-2-ol) and octa(1,3-bis[2-(2-ethoxyethoxy)ethoxy]propan-2-ol) were synthesized by cyclotetramerisation of the corresponding nitriles. At room temperature, α-substituted Ni(II) phthalocyanine complexes exhibited a relatively viscous liquid state; their spectroscopic properties aggregation behaviour investigated in different solvents at concentrations chloroform. The two compounds showed Q-bands near-IR region electronic spectrum did not aggregate all under wide range
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