Surface grafting of hyperbranched dendritic polymer onto glass fiber
作者： Kazuhiro Fujiki , Munenori Sakamoto , Sachio Yoshikawa , Toshiya Sato , Norio Tsubokawa
关键词: Methyl acrylate 、 Polymer chemistry 、 Michael reaction 、 Ethylenediamine 、 Amination 、 Glass fiber 、 Polymer 、 Materials science 、 Hexamethylenediamine 、 Grafting
摘要: This paper describes surface grafting of hyperbranched dendritic polyamidoamine, a new class topological macromolecules, onto glass fiber for modification the surface. Glass having amino groups as initiator sites was prepared by treatment with 3-aminopropyltriethoxysilane. Grafting reaction polyamidoamine from achieved repeating Michael addition methyl acrylate to followed amination end groups, which is resulting ester moieties ethylenediamine or hexamethylenediamine. Both amount terminal and percentage increased an increase in number generations. Ethylenediamine reactant more effective than hexamethylenediamine propagation polyamidoamine. However, fiber...
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