Hydrogen Storage in Metal-Organic Frameworks

作者: Yubiao Sun , Li Wang , Wael A. Amer , Haojie Yu , Jing Ji

DOI: 10.1007/S10904-012-9779-4

关键词: HydrogenHydrogen storageHybrid materialSurface modificationChemistryMetal-organic frameworkHigh surfaceStructural diversityNanotechnologyMolecular simulationInorganic chemistryMaterials ChemistryPolymers and Plastics

摘要: Recent decades have witnessed the explosive emergence of metal organic frameworks (MOFs) as functional ultrahigh surface area materials. Categorized an intriguing class hybrid materials, MOFs exhibit infinite crystalline lattices with inorganic vertices and molecular-scale linkers. Fortunately, large internal areas overall pore volumes, adjustable sizes, ultralow densities, tunable framework–adsorbate interaction by ligand functionalization choice, enable to be promising materials for wide applications. In particular, these remarkable properties render potential hydrogen storage By virtue their exceptionally high areas, unparalleled tenability structural diversity, become a hotspot research within scientific community. This paper reviews different methods used synthesis MOFs, relationship between features adsorption, strategies uptake improvement well molecular simulation.

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