Ion specificities of artificial macromolecules
作者： Lvdan Liu , Ran Kou , Guangming Liu
DOI: 10.1039/C6SM01773H
关键词: Aqueous solution 、 Chemical physics 、 Chemistry 、 Nanotechnology 、 Macromolecule 、 Solvent 、 Polymer 、 Ion
摘要: Artificial macromolecules are well-defined synthetic polymers, with a relatively simple structure as compared to naturally occurring macromolecules. This review focuses on the ion specificities of artifical Ion influenced by solvent-mediated indirect ion–macromolecule interactions and also direct interactions. In aqueous solutions, role water-mediated will be discussed. The addition organic solvents solutions significantly changes due formation water–organic solvent complexes. For interactions, we discuss specific ion-pairing for charged ion–neutral site uncharged When medium conditions change from dilute crowded environments, can modified either volume exclusion effect, variation dielectric constant, or between ions, macromolecules, crowding agents.
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