Synthesis and metal complexation of a functional fullerene containing amine, phosphine, and pyridine coordinate groups
作者： Jang-Yun Yeh , Wen-Yann Yeh
DOI: 10.1016/J.JORGANCHEM.2016.10.025
关键词: Stereochemistry 、 Yield (chemistry) 、 Benzaldehyde 、 Chemistry 、 Pyridine 、 Amine gas treating 、 Derivative (chemistry) 、 Metal 、 Medicinal chemistry 、 Phosphine 、 Fullerene
摘要: Abstract Treating C60 with o-(diphenylphosphino)benzaldehyde and o-aminomethylpyridine in refluxing o-dichlorobenzene affords a new fullerene derivative syn-PPh2(o-C6H4)(o-C5H4N)(C2H3NC60) (1) moderate yield. Compound 1 displays versatile coordination modes. Such that, reactions of with Os3(CO)11(NCMe), W(CO)4(NCMe)2, Ru3(CO)12 produce Os3(CO)11(η1-PPh2(o-C6H4)(o-C5H4N)(C2H3NC60)) (2), W(CO)4(η2-PPh2(o-C6H4)(o-C5H4N)(C2H3NC60)) (3), Ru(CO)3(η3-PPh2(o-C6H4)(o-C5H4N)(C2H3NC60)) (4), respectively. Interestingly, heating 4 leads to transfer the addend give tetraruthenium cluster complex (μ-H)Ru4(CO)11(μ4,η4-PPh2(o-C6H4)CH2NC(o-C5H4N)) (5). The structures 5 have been determined by an X-ray diffraction study.
sci-hub.se 参考文章(32)
Stefan Brammer, Anke Krüger, Carbon Materials and Nanotechnology ,(2010)
Fullerenes : principles and applications Royal Society of Chemistry. ,(2007) , 10.1039/9781847557711
Robert H. Crabtree, The organometallic chemistry of the transition metals ,(1988)
Helmut Fischer, Siegfried Zeuner, Kinetische und mechanistische untersuchungen von übergangsmetall-komplex-reaktionen XXII. Konkurrenz zwischen dissoziativem und assoziativem mechanismus bei der reaktion von pentacarbonyl(diphenylcarben)wolfram mit nitrilen Journal of Organometallic Chemistry. ,vol. 327, pp. 63- 75 ,(1987) , 10.1016/0022-328X(87)80228-0
Chia-Hsiang Chen, Wen-Yann Yeh, None, Re–Re bond breaking of (μ-H)3Re3(CO)11(NCMe) upon reaction with PPh2(o-C6H4)(CH2NMeCH)C60 to generates monorhenium and dirhenium phosphino–fullerene complexes Dalton Transactions. ,vol. 42, pp. 2488- 2494 ,(2013) , 10.1039/C2DT32291A
Pavel A. Troshin, Alexander S. Peregudov, David Mühlbacher, Rimma N. Lyubovskaya, An Efficient [2+3] Cycloaddition Approach to the Synthesis of Pyridyl‐Appended Fullerene Ligands European Journal of Organic Chemistry. ,vol. 2005, pp. 3064- 3074 ,(2005) , 10.1002/EJOC.200500048
Chia-Hsiang Chen, Wen-Yann Yeh, None, Synthesis and characterization of fullerophosphine–Au(I) complexes Journal of Organometallic Chemistry. ,vol. 784, pp. 41- 45 ,(2015) , 10.1016/J.JORGANCHEM.2014.05.037
Wen-Yann Yeh, Kune-You Tsai, Complexation and C−H/C−P Bond Activation of the (PPh2)C60H Molecule on Triosmium Carbonyl Clusters Organometallics. ,vol. 29, pp. 604- 609 ,(2010) , 10.1021/OM900914A
Ching-Chao Yang, Wen-Yann Yeh, Gene-Hsiang Lee, Shie-Ming Peng, Syntheses, characterization and structures of chromium group carbonyl complexes containing a multifunctional Ph2P(o-C6H4)CHN(CH2)2(o-C6H4N) ligand Journal of Organometallic Chemistry. ,vol. 598, pp. 353- 358 ,(2000) , 10.1016/S0022-328X(99)00734-2
Wen-Yann Yeh, Synthesis and characterization of face-capping triruthenium cluster complexes of pentamethylfullerenes Journal of Organometallic Chemistry. ,vol. 751, pp. 351- 355 ,(2014) , 10.1016/J.JORGANCHEM.2013.06.009