Re–Re bond breaking of (μ-H)3Re3(CO)11(NCMe) upon reaction with PPh2(o-C6H4)(CH2NMeCH)C60 to generates monorhenium and dirhenium phosphino–fullerene complexes
作者： Chia-Hsiang Chen , Wen-Yann Yeh , None
DOI: 10.1039/C2DT32291A
关键词:
摘要: Reaction of PPh2(o-C6H4)(CH2NMeCH)C60 (1) and (μ-H)3Re3(CO)11(NCMe) in refluxing chlorobenzene affords the monorhenium complex HRe(CO)3(η3-PPh2(o-C6H4)(CH2NMeCH)C60) (2), dirhenium complexes (μ-H)Re2(CO)7(μ,η3-PPh(o-C6H4)2(CH2NMeCH)C60) (3) (μ-H)Re2(CO)5(μ-SSOH)(μ,η5-PPh2(o-C6H4)(CH2NMeCH)C60) (4). The structures 2–4 have been determined by an X-ray diffraction study. oxatrisulfanyl (–SSOH) ligand 4 likely arises from decomposition CS2 on silica gel during purification processes.
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sci-hub.se 参考文章(47)
H. W. Kroto, J. R. Heath, S. C. O’Brien, R. F. Curl, R. E. Smalley, C 60 : Buckminsterfullerene Nature. ,vol. 318, pp. 162- 163 ,(1985) , 10.1038/318162A0
Shulin Zhang, Theodore L. Brown, Yuhua Du, John R. Shapley, Metalation of fullerene (C60) with pentacarbonylrhenium radicals. Reversible formation of C60{Re(CO)5}2 Journal of the American Chemical Society. ,vol. 115, pp. 6705- 6709 ,(1993) , 10.1021/JA00068A030
Stefan Brammer, Anke Krüger, Carbon Materials and Nanotechnology ,(2010)
Fullerenes : principles and applications Royal Society of Chemistry. ,(2007) , 10.1039/9781847557711
Richard D. Adams, Burjor Captain, Perry J. Pellechia, Studies of Ligand Additions to Coordinatively Unsaturated Dirhenium Complexes Containing the Bulky PBut3 Ligand Organometallics. ,vol. 26, pp. 6564- 6575 ,(2007) , 10.1021/OM700790C
Barry C. Thompson, Jean M. J. Fréchet, Polymer–Fullerene Composite Solar Cells Angewandte Chemie. ,vol. 47, pp. 58- 77 ,(2008) , 10.1002/ANIE.200702506
Wen-Yann Yeh, Kune-You Tsai, Complexation and C−H/C−P Bond Activation of the (PPh2)C60H Molecule on Triosmium Carbonyl Clusters Organometallics. ,vol. 29, pp. 604- 609 ,(2010) , 10.1021/OM900914A
Piero Zanello, Franco Laschi, Marco Fontani, Li-Cheng Song, Ying-Huai Zhu, Redox behavior of the molybdenum and tungsten metallafullerenes Mo(CO)3(dppe)(η2-C60) (dppe=bis-(1,2-diphenylphosphino)ethane) and W(CO)3(dppb)(η2-C60) (dppb=bis-(1,2-diphenylphosphino)benzene) Journal of Organometallic Chemistry. ,vol. 593, pp. 7- 11 ,(2000) , 10.1016/S0022-328X(99)00325-3
J.P. Hare, H.W. Kroto, R. Taylor, Preparation and UV / visible spectra of fullerenes C60 and C70 Chemical Physics Letters. ,vol. 177, pp. 394- 398 ,(1991) , 10.1016/0009-2614(91)85072-5
Takeshi Akasaka, Wataru Ando, Kaoru Kobayashi, Shigeru Nagase, Reaction of C60 with silylene, the first fullerene silirane derivative Journal of the American Chemical Society. ,vol. 115, pp. 1605- 1606 ,(1993) , 10.1021/JA00057A072