Controlled/“Living” Radical Polymerization. Kinetics of the Homogeneous Atom Transfer Radical Polymerization of Styrene

作者： Krzysztof Matyjaszewski , Timothy E. Patten , Jianhui Xia

关键词: Chain transfer 、 Atom-transfer radical-polymerization 、 Polymer chemistry 、 Radical polymerization 、 Bulk polymerization 、 Photochemistry 、 Chemistry 、 Anionic addition polymerization 、 Reversible addition−fragmentation chain-transfer polymerization 、 Cobalt-mediated radical polymerization 、 Living free-radical polymerization

摘要: … radical polymerization is atom transfer radical polymerization (ATRP). In this polymerization … ) activates reversibly the dormant polymer chains via a halogen atom transfer reaction (eq 1), …