Photo-excited state of N-benzyl MNA studied by femtosecond time-resolved absorption spectroscopy

作者: Atsushi Sugita , Kazuhiro Yanagi , Kazuyoshi Kuroyanagi , Hironori Takahashi , Shinichiro Aoshima

DOI: 10.1016/J.CPLETT.2003.10.115

关键词: Stimulated emissionExcited stateUltrashort pulseGround stateAnalytical chemistryFemtosecondAtomic physicsRelaxation (NMR)Time-resolved spectroscopyAbsorption spectroscopyChemistry

摘要: Ultrafast photo-excitation dynamics of N-benzyl 2-methyl-4-nitroaniline was studied with femtosecond time-resolved absorption spectroscopy. The photo-induced spectrum found to consist three transient components different decay times. A 260 fs-decay time stimulated emission appeared during a geometrical relaxation from charge-transfer excited state geometrically relaxed state. following energy the completed within 680 fs. Third 2.6 ps reflected cooling process hot electrons in ground potential.

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