Metal-Metal Bonds and Metal Carbon Bonds in the Chemistry of Molybdenum and Tungsten Alkoxides.

作者: Malcolm H. Chisholm

DOI: 10.1016/S0277-5387(00)87197-1

关键词: ChemistryPi backbondingChemical bondMolecular orbitalMetalReactivity (chemistry)Delocalized electronAlkoxidePhotochemistrySteric effects

摘要: … chemistry of molybdenum and tungsten. Except in the oxidation state +6, where the metal … (1) Tungsten binds Lewis bases more tightly for a given alkoxy group, eg as in the isolation …

参考文章(64)
Malcolm H. Chisholm, Ian P. Rothwell, Chemical Reactions of Metal-Metal Bonded Compounds of the Transition Elements Progress in Inorganic Chemistry. ,vol. 13, pp. 1- 72 ,(2007) , 10.1002/9780470166307.CH1
Roger N. McGinnis, Timothy R. Ryan, R. E. McCarley, Reactions of activated quadruply bonded molybdenum dimers. Formation of new rectangular clusters containing the tetrametal analog of cyclobutadiyne Journal of the American Chemical Society. ,vol. 100, pp. 7900- 7902 ,(1978) , 10.1021/JA00493A019
D.C. Bradley, Metal oxide alkoxide (trialkylsilyloxide) polymers Coordination Chemistry Reviews. ,vol. 2, pp. 299- 318 ,(1967) , 10.1016/S0010-8545(00)80126-5
Malcolm H. Chisholm, F. Albert Cotton, Chemistry of compounds containing metal-to-metal triple bonds between molybdenum and tungsten Accounts of Chemical Research. ,vol. 10, pp. 356- 362 ,(1978) , 10.1021/AR50129A006
Lloyd J. Guggenberger, A. W. Sleight, Structural and bonding characterizations of molybdenum dibromide, Mo6Br12.2H2O Inorganic Chemistry. ,vol. 8, pp. 2041- 2049 ,(1969) , 10.1021/IC50080A001
Peter C. Healy, David L. Kepert, Donald Taylor, Allan H. White, Crystal structure of dicaesium octa-µ3-chloro-hexachloro-octahedro-hexa-tungstate(II) and -molybdate(II) complexes J. Chem. Soc., Dalton Trans.. ,vol. 1973, pp. 646- 650 ,(1973) , 10.1039/DT9730000646
Anthony K. Rappe, William A. Goddard, Olefin metathesis - a mechanistic study of high-valent Group VI catalysts Journal of the American Chemical Society. ,vol. 104, pp. 448- 456 ,(1982) , 10.1021/JA00366A013