Detection of morphotropic phase boundary of (Bi1/2Na1/2)TiO3–Ba(Al1/2Sb1/2)O3 solid-solution ceramics
作者： Yuji Hiruma , Hajime Nagata , Tadashi Takenaka
DOI: 10.1063/1.3194146
关键词: Fabrication 、 Mineralogy 、 Phase diagram 、 Ferroelectric ceramics 、 Phase boundary 、 Trigonal crystal system 、 Materials science 、 Materials preparation 、 Solid solution 、 Analytical chemistry 、 Ceramic
摘要: A solid-solution system, (1−x)(Bi1/2Na1/2)TiO3–xBa(Al1/2Sb1/2)O3 (BNT-BAS100x), was fabricated by a conventional ceramic fabrication process. The morphotropic phase boundary (MPB) between rhombohedral and pseudocubic phases of BNT-BAS100x clarified to be at approximately x=0.045, the highest normalized strain d33* 532 pm/V obtained this composition. This study also revealed that MPB composition BNT-based solid solution shifts BNT-rich as tolerance factor t end member increases, is always 0.983. indicates position can predicted from values members.
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sci-hub.se 参考文章(12)
N Setter, Piezoelectric materials in devices N. Setter. ,(2002)
Sossity A. Sheets, Andrey N. Soukhojak, Naoki Ohashi, Yet-Ming Chiang, Relaxor single crystals in the (Bi1/2Na1/2)1−xBaxZryTi1−yO3 system exhibiting high electrostrictive strain Journal of Applied Physics. ,vol. 90, pp. 5287- 5295 ,(2001) , 10.1063/1.1410325
Lang Wu, Dingquan Xiao, Dunmin Lin, Jianguo Zhu, Ping Yu, Xiang Li, Temperature Dependence of Electric Properties of [Bi0.5(Na1-xAgx)0.5]1-yBayTiO3 Ceramics Japanese Journal of Applied Physics. ,vol. 46, pp. 7382- 7387 ,(2007) , 10.1143/JJAP.46.7382
Yuji Hiruma, Hajime Nagata, Tadashi Takenaka, Phase diagrams and electrical properties of (Bi1/2Na1/2)TiO3-based solid solutions Journal of Applied Physics. ,vol. 104, pp. 124106- ,(2008) , 10.1063/1.3043588
Matthew R. Suchomel, Peter K. Davies, Predicting the position of the morphotropic phase boundary in high temperature PbTiO3-Bi(B′B″)O3 based dielectric ceramics Journal of Applied Physics. ,vol. 96, pp. 4405- 4410 ,(2004) , 10.1063/1.1789267
Yuji Hiruma, Hajime Nagata, Tadashi Takenaka, Phase Transition Temperatures and Piezoelectric Properties of (Bi1/2Na1/2)TiO3–(Bi1/2K1/2)TiO3–BaTiO3 Lead-Free Piezoelectric Ceramics Japanese Journal of Applied Physics. ,vol. 45, pp. 7409- 7412 ,(2006) , 10.1143/JJAP.45.7409
Dunmin Lin, Dingquan Xiao, Jianguo Zhu, Ping Yu, Piezoelectric and ferroelectric properties of [Bi0.5(Na1−x−yKxLiy)0.5]TiO3 lead-free piezoelectric ceramics Applied Physics Letters. ,vol. 88, pp. 062901- ,(2006) , 10.1063/1.2171799
G. O. Jones, P. A. Thomas, The tetragonal phase of Na0.5Bi0.5TiO3 – a new variant of the perovskite structure Acta Crystallographica Section B-structural Science. ,vol. 56, pp. 426- 430 ,(2000) , 10.1107/S0108768100001166
E. A. Wood, Polymorphism in potassium niobate, sodium niobate, and otherABO3compounds Acta Crystallographica. ,vol. 4, pp. 353- 362 ,(1951) , 10.1107/S0365110X51001112
Seung-Eek Park, Kug Sun Hong, Variations of Structure and Dielectric Properties on Substituting A-site Cations for Sr2+ in (Na1/2Bi1/2)TiO3 Journal of Materials Research. ,vol. 12, pp. 2152- 2157 ,(1997) , 10.1557/JMR.1997.0288