Regulation of coal flotation by the cations in the presence of clay

作者: Haoyu Bai , Yiping Liu , Yunliang Zhao , Tianxing Chen , Hongqiang Li

DOI: 10.1016/J.FUEL.2020.117590

关键词: Chemical engineeringInteraction energyDLVO theoryClay mineralsCoalCoatingChemistry

摘要: Abstract The concomitant clay minerals in coal commonly have adverse effects on the flotation. In this work, regulation of flotation by cations (Na+ and K+) presence was investigated to abate deterioration. It observed SEM-EDS that particles coating surface low pH condition, which significantly reduced hydrophobicity coal. However, after introducing K+), originally adhering fall off form large aggregates. addition Na+ K+ affected DLVO interaction energy between clay, making attracting tendency clays stronger than attraction Moreover, cation species different behaviors. improves combustible recovery inhibiting coating. While, mainly promotes aggregation inhibits clay. Thermodynamic simulating calculation shows combination will release more heat is also conducive hinder obtained behavior rules mechanisms using regulating can help decouple effect clean production coal, especially water-deficient coastal areas.

参考文章(37)
KP Galvin, NG Harvey, JE Dickinson, None, Fluidized bed desliming in fine particle flotation – Part III flotation of difficult to clean coal Minerals Engineering. pp. 94- 101 ,(2014) , 10.1016/J.MINENG.2014.02.008
Bulelwa Ndlovu, Saeed Farrokhpay, Dee Bradshaw, The effect of phyllosilicate minerals on mineral processing industry International Journal of Mineral Processing. ,vol. 125, pp. 149- 156 ,(2013) , 10.1016/J.MINPRO.2013.09.011
A Chakraborty, BB Saha, S Koyama, KC Ng, None, On the thermodynamic modeling of the isosteric heat of adsorption and comparison with experiments Applied Physics Letters. ,vol. 89, pp. 171901- ,(2006) , 10.1063/1.2360925
G. Marrucci, L. Nicodemo, Coalescence of gas bubbles in aqueous solutions of inorganic electrolytes Chemical Engineering Science. ,vol. 22, pp. 1257- 1265 ,(1967) , 10.1016/0009-2509(67)80190-8
Bo Wang, Yongjun Peng, Sue Vink, Diagnosis of the Surface Chemistry Effects on Fine Coal Flotation Using Saline Water Energy & Fuels. ,vol. 27, pp. 4869- 4874 ,(2013) , 10.1021/EF400909R
P. George, A.V. Nguyen, G.J. Jameson, Assessment of true flotation and entrainment in the flotation of submicron particles by fine bubbles Minerals Engineering. ,vol. 17, pp. 847- 853 ,(2004) , 10.1016/J.MINENG.2004.02.002
Vishal Gupta, Marc A. Hampton, Jason R. Stokes, Anh V. Nguyen, Jan D. Miller, Particle interactions in kaolinite suspensions and corresponding aggregate structures Journal of Colloid and Interface Science. ,vol. 359, pp. 95- 103 ,(2011) , 10.1016/J.JCIS.2011.03.043