A chiral screw propeller-like scalene triangle manganese(III) cluster.
作者： Cai-Ming Liu , De-Qing Zhang , Dao-Ben Zhu
DOI: 10.1039/B913062D
关键词: Antiferromagnetism 、 Crystallography 、 Cluster (physics) 、 Magnetic anisotropy 、 Ion 、 Manganese 、 Stereochemistry 、 Chemistry 、 Ferromagnetism 、 Scalene triangle
摘要: The screw propeller-like cluster complex [Mn3(OMe)(LSchiff)3(H2O)Cl2]·2H2O {H2LSchiff = 2-[(E)-(R)-1-hydroxypropan-2-ylimino]methyl-6-methoxyphenol} is the first chiral triangle manganese compound. It also a rare nonsymmetrical compound with an unequilateral arrangement of three manganese(III) atoms. Both ferromagnetic and antiferromagnetic interactions exist between Mn3+ ions, exhibiting magnetic anisotropy.
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