Occurrence of soluble organic compounds in thermal waters by ion trap mass detection

作者: C. González-Barreiro , B. Cancho-Grande , P. Araujo-Nespereira , J.A. Cid-Fernández , J. Simal-Gándara

DOI: 10.1016/J.CHEMOSPHERE.2008.11.067

关键词: Mass spectrometryExtraction (chemistry)Solid phase extractionWater qualityElectron ionizationIon trapEnvironmental chemistryLiquid–liquid extractionGas chromatographyChemistry

摘要: Abstract Thermal waters can be regarded as worth developing because of their human health implications and, if thermal tourism is promoted, importance to the local economy. Galicia, in North-West Spain, has numerous sources spread all over region. They have been used for therapeutic purposes since Roman times. Ourense, with 82 (9 spas), becoming one richest Spanish provinces hydromineral and resources. In this work, most representative springs from city Ourense – Outariz, Chavasqueira, Tinteiro As Burgas were analysed order identify presence several chemical classes soluble organic compounds responsible biological activity. The studied are hyperthermal, temperatures ranged between 45 66 °C. Different extraction techniques, liquid–liquid (LLE), solid phase (SPE) micro-extraction (SPME), combined gas chromatography–electron impact ion trap mass spectrometry (GC–(EI)ITMS) cover a wide variety compounds. characteristic families extractable detected thoroughly discussed. Most substances belonging phenol, aldehyde, esther, ketone, elemental sulphur groups occur samples. Large amounts found spring, providing water beneficial clinical effects.

参考文章(27)
M. Brault, B.R.T. Simoneit, J.C. Marty, A. Saliot, Hydrocarbons in waters and particulate material from hydrothermal environments at the East Pacific Rise, 13°N Organic Geochemistry. ,vol. 12, pp. 209- 219 ,(1988) , 10.1016/0146-6380(88)90259-8
J. Virgílio Cruz, Zilda França, Hydrogeochemistry of thermal and mineral water springs of the Azores archipelago (Portugal) Journal of Volcanology and Geothermal Research. ,vol. 151, pp. 382- 398 ,(2006) , 10.1016/J.JVOLGEORES.2005.09.001
�. Gemici, G. Tarcan, Hydrogeological and hydrogeochemical features of the Heybeli Spa, Afyon, Turkey: arsenic and the other contaminants in the thermal waters. Bulletin of Environmental Contamination and Toxicology. ,vol. 72, pp. 1107- 1114 ,(2004) , 10.1007/S00128-004-0358-4
Josep M Bayona, Amanda Monjonell, Juan Carlos Miquel, Scott W Fowler, Joan Albaigés, Biogeochemical characterization of particulate organic matter from a coastal hydrothermal vent zone in the Aegean Sea Organic Geochemistry. ,vol. 33, pp. 1609- 1620 ,(2002) , 10.1016/S0146-6380(02)00175-4
Polona Kralj, Chemical composition of low temperature (<20–40 °C) thermal waters in Slovenia Environmental Earth Sciences. ,vol. 46, pp. 635- 642 ,(2004) , 10.1007/S00254-004-1001-8