Dative Bonding between Group 13 Elements Using a Boron-Centered Lewis Base.
作者： Holger Braunschweig , Rian D. Dewhurst , Leanne Pentecost , Krzysztof Radacki , Alfredo Vargas
关键词: Lewis acid catalysis 、 Lewis acids and bases 、 Chemistry 、 Nanotechnology 、 Adduct 、 Donor number 、 Boron group 、 Nitrogen 、 Frustrated Lewis pair 、 Boron 、 Polymer chemistry
摘要: An electron-rich monovalent boron compound is used as a Lewis base to prepare adducts with Group 13 acids using both its and nitrogen sites. The hard acid AlCl3 binds through atom of the base, while softer GaX3 (Cl, Br, I) bind at atom. latter are first noncluster between boron-centered main-group acid.
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sci-hub.se 参考文章(91)
Bochao Su, Yongxin Li, Rakesh Ganguly, Jenny Lim, Rei Kinjo, Isolation and Reactivity of 1,4,2-Diazaborole Journal of the American Chemical Society. ,vol. 137, pp. 11274- 11277 ,(2015) , 10.1021/JACS.5B07823
Holger Braunschweig, Theresa Dellermann, William C. Ewing, Thomas Kramer, Christoph Schneider, Stefan Ullrich, Reduktive Insertion von elementaren Chalkogenen in Bor‐Bor‐ Mehrfachbindungen Angewandte Chemie. ,vol. 127, pp. 10409- 10413 ,(2015) , 10.1002/ANGE.201503398
Holger Braunschweig, Rian D. Dewhurst, Florian Hupp, Marco Nutz, Krzysztof Radacki, Christopher W. Tate, Alfredo Vargas, Qing Ye, Multiple complexation of CO and related ligands to a main-group element Nature. ,vol. 522, pp. 327- 330 ,(2015) , 10.1038/NATURE14489
T. B. Marder, Boron Goes On the Attack Science. ,vol. 314, pp. 69- 70 ,(2006) , 10.1126/SCIENCE.1133326
Philipp Bissinger, Holger Braunschweig, Mehmet Ali Celik, Christina Claes, Rian D. Dewhurst, Sebastian Endres, Hauke Kelch, Thomas Kramer, Ivo Krummenacher, Christoph Schneider, Synthesis of cyclic diborenes with unprecedented cis-configuration Chemical Communications. ,vol. 51, pp. 15917- 15920 ,(2015) , 10.1039/C5CC07103H
Y. Segawa, M. Yamashita, K. Nozaki, Boryllithium: Isolation, Characterization, and Reactivity as a Boryl Anion Science. ,vol. 314, pp. 113- 115 ,(2006) , 10.1126/SCIENCE.1131914
Ned J. Hardman, Robert J. Wright, Andrew D. Phillips, Philip P. Power, Structures, Bonding, and Reaction Chemistry of the Neutral Organogallium(I) Compounds (GaAr)n (n = 1 or 2) (Ar = Terphenyl or Related Ligand): An Experimental Investigation of Ga−Ga Multiple Bonding Journal of the American Chemical Society. ,vol. 125, pp. 2667- 2679 ,(2003) , 10.1021/JA028579J
Kevin Yurkerwich, Daniela Buccella, Jonathan G. Melnick, Gerard Parkin, Tris(2-mercapto-1-tert-butylimidazolyl)hydroborato gallium derivatives: synthesis of di- and trigallium compounds in a sulfur-rich coordination environment Chemical Science. ,vol. 1, pp. 210- 214 ,(2010) , 10.1039/C0SC00145G
Roland C. Fischer, Philip P. Power, π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium Chemical Reviews. ,vol. 110, pp. 3877- 3923 ,(2010) , 10.1021/CR100133Q
Tom Ziegler, Arvi Rauk, Evert J. Baerends, On the calculation of multiplet energies by the hartree-fock-slater method Theoretical Chemistry Accounts. ,vol. 43, pp. 261- 271 ,(1977) , 10.1007/BF00551551