Triplet-sensitized deoxygenation reaction of 6-cyanophenanthridine 5-oxide in ethanol
作者： Kunihiro Tokumura , Yumi Matsushita
DOI: 10.1016/S1010-6030(01)00387-2
关键词: Photochemistry 、 Chemistry 、 Ultrafast laser spectroscopy 、 Oxide 、 Triplet state 、 Absorption band 、 Proflavine 、 Reaction intermediate 、 Deoxygenation 、 Absorption (chemistry)
摘要: Abstract Deoxygenation of 6-cyanophenanthridine 5-oxide (6CPNO) in the lowest triplet state was confirmed by sensitization proflavine with visible S 1 ←S 0 absorption band ( λ max =460 nm) ethanol. Absorption bands (6CP) grew up at expense those N -oxide a selective steady-light (>420 nm) irradiation presence -oxide. In 460 nm laser pulse excitation proflavine, furthermore, weak transient due to sensitized detected around 410 nm.
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