The photoinduced deoxygenation reaction of heterocyclic N-oxides.

作者: Norisuke Hata , Isao Ono , Masao Kawasaki

DOI: 10.1246/CL.1975.25

关键词:

摘要: The azanaphthalene N-oxides underwent the photochemical deoxygenation reaction in benzene containing BF3-etherate, resulting formation of parent amines a 70–80% yield. triplet sensitizations quinoline-, isoquinoline-, and acridine-N-oxides by biacetyl or eosin also led to dissociation N–O bond.

参考文章(3)
Norisuke Hata, Ikuzo Tanaka, Chemical Processes Subsequent ton—π*and π—π*Transitions of PyridineN‐oxide and 2‐PicolineN‐oxide The Journal of Chemical Physics. ,vol. 36, pp. 2072- 2077 ,(1962) , 10.1063/1.1732830
Tanekazu Kubota, Masumi Yamakawa, Yoshiko Mizuno, The Singlet-triplet Absorption Spectra of Heterocyclic AmineN-Oxides (I) Bulletin of the Chemical Society of Japan. ,vol. 45, pp. 3282- 3286 ,(1972) , 10.1246/BCSJ.45.3282
Gavin G. Spence, Edward Curtis. Taylor, Ole. Buchardt, Photochemical reactions of azoxy compounds, nitrones, and aromatic amine N-oxides Chemical Reviews. ,vol. 70, pp. 231- 265 ,(1970) , 10.1021/CR60264A003