Structure and properties of a compatible starch‐PCL composite using p‐phthaloyl chloride‐based prepolymer
作者： Ting Liu , Ernest Koranteng , Zhengshun Wu , Wang Xiao , Qiangxian Wu
DOI: 10.1002/APP.45400
关键词: Chemical structure 、 Absorption of water 、 Chemical engineering 、 Prepolymer 、 Composite number 、 Chloride 、 Polycaprolactone 、 Starch 、 Crystallinity 、 Materials science 、 Composite material
摘要: Biodegradable composites from starch and hydrophobic polymer usually show poor compatibility. A novel p-phthaloyl chloride-based prepolymer (PCP) compatibilizer based on chloride polycaprolactone (PCL) diol (2000) was synthesized successfully the chemical structure characterized by Fourier transform infrared spectra 1H nuclear magnetic resonance (NMR). The PCP compatiblizer mixed with granules to form a coating layer, then coated were melt-compounded PCL plastic prepare compatible starch-PCL enhanced properties. structural, mechanical, thermal properties, water absorption of investigated. It found that containing showed better interfacial interaction compatibility between domains compared pure composite, which led improved mechanical properties composites. results attributed ester linkage as well strong physical crosslinking through PCL-PCL crystallinity. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 45400.
sci-hub.se 参考文章(36)
G.A. Arolkar, M.J. Salgo, V. Kelkar-Mane, R.R. Deshmukh, The study of air-plasma treatment on corn starch/poly(ε-caprolactone) films Polymer Degradation and Stability. ,vol. 120, pp. 262- 272 ,(2015) , 10.1016/J.POLYMDEGRADSTAB.2015.07.016
M. P. Guarás, V. A. Alvarez, L. N. Ludueña, Processing and characterization of thermoplastic starch/polycaprolactone/compatibilizer ternary blends for packaging applications Journal of Polymer Research. ,vol. 22, pp. 165- ,(2015) , 10.1007/S10965-015-0817-0
Ana Antonieta Chew-Guevara, Esther Pérez-Carrillo, Sergio Román Othon Serna-Saldívar, Julián de la Rosa-Millán, Effect of decortication and protease treatment on physicochemical and functional characteristics of red sorghum (Sorghum bicolor) and yellow maize (Zea maiz) starches Starch-starke. ,vol. 68, pp. 1- 8 ,(2016) , 10.1002/STAR.201500151
DR Lu, CM Xiao, SJ Xu, None, Starch-based completely biodegradable polymer materials Express Polymer Letters. ,vol. 3, pp. 366- 375 ,(2009) , 10.3144/EXPRESSPOLYMLETT.2009.46
P. A. Perry, A. M. Donald, The role of plasticization in starch granule assembly. Biomacromolecules. ,vol. 1, pp. 424- 432 ,(2000) , 10.1021/BM0055145
S WANG, L LU, J GRUETZMACHER, B CURRIER, M YASZEMSKI, Synthesis and characterizations of biodegradable and crosslinkable poly(ε-caprolactone fumarate), poly(ethylene glycol fumarate), and their amphiphilic copolymer Biomaterials. ,vol. 27, pp. 832- 841 ,(2006) , 10.1016/J.BIOMATERIALS.2005.07.013
Jerzy Korol, Joanna Lenża, Krzysztof Formela, Manufacture and research of TPS/PE biocomposites properties Composites Part B: Engineering. ,vol. 68, pp. 310- 316 ,(2015) , 10.1016/J.COMPOSITESB.2014.08.045
M. Gáspár, Zs. Benkő, G. Dogossy, K. Réczey, T. Czigány, Reducing water absorption in compostable starch-based plastics Polymer Degradation and Stability. ,vol. 90, pp. 563- 569 ,(2005) , 10.1016/J.POLYMDEGRADSTAB.2005.03.012
Jingjing Liao, Zimu Luo, Yu Zhang, Xu Zhang, Jing Cheng, Qiangxian Wu, Effects of a novel compatible interface structure on the properties of starch–PCL composites New Journal of Chemistry. ,vol. 38, pp. 2522- 2529 ,(2014) , 10.1039/C3NJ01647A
Gholam Ali Koohmareh, Hamid Reza Fallah, Farhad Farnia, Synthesis, characterization, and optical properties of poly[2-(4-(2,2′-bithiophen-5-yl)phenyl)-4-(4-alkoxyphenyl)-6-phenylpyridine]s Designed Monomers and Polymers. ,vol. 17, pp. 401- 415 ,(2014) , 10.1080/15685551.2013.840516