Photo-stimulated charge carrier transport in a polydiacetylene single crystal (PTS)

作者: T Blum , B Ries , H Bassler

DOI: 10.1088/0022-3719/19/19/020

关键词: Quantum tunnellingExcited stateCharge carrierLight intensitySingle crystalOptoelectronicsRelaxation (NMR)Molecular physicsExcitationMaterials scienceCrystal

摘要: The rise time behaviour of photocurrents in a PTS crystal excited by rectangular light pulses has been measured and the rate constant K(t) charge carrier relaxation evaluated. At short times (t 10-2 s) follows power law characteristic transport controlled tunnelling barriers. intermediate K attains value that increases with intensity according to Kopt approximately I0.85. effect is explained terms an interaction between delocalised optical excitation chain localised at defect. It concluded photo-simulated barrier crossing rate-determining step for presence photon field.

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