Determination of Abraham model solute descriptors for three dichloronitrobenzenes from measured solubilities in organic solvents
作者： Michela Brumfield , Akash Wadawadigi , Napasorn Kuprasertkul , Sumedha Mehta , Timothy W. Stephens
DOI: 10.1080/00319104.2014.972555
关键词: Character (mathematics) 、 Mole fraction 、 Solubility 、 Standard deviation 、 Polarity (physics) 、 Physical chemistry 、 Chemistry 、 Thermodynamics
摘要: Mole fraction solubilities are reported for 1,4-dichloro-2-nitrobenzene dissolved in 24 organic solvents of varying polarity and hydrogen-bonding character. The experimental data used to calculate Abraham solute descriptors. calculated descriptors describe the within an overall average standard deviation 0.081 log units. Also manuscript model both 3,4-dichloro-1-nitrobenzene 2,3-dichloro-1-nitrobenzene based on published literature data.
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