Study of thermal dehydration of sodium orthophosphate monosubstituted

作者: Anna Cheremysinova , Irina Sknar , Yaroslav Kozlov , Olga Sverdlikovska , Oleksii Sigunov

DOI: 10.15587/1729-4061.2017.100982

关键词: Isothermal processColumn chromatographyInorganic chemistryThermogravimetric analysisComposition (visual arts)Salt (chemistry)ChemistryPhosphateDehydrationKinetics

摘要: Depending on the conditions of conducting synthesis, it is possible to obtain polymeric phosphates different composition and structure. The mixtures polyphosphates, employed in production technological lubricants, are expedient synthesize by high-temperature dehydration sodium orthophosphate monosubstituted. temperature ranges, over which thermochemical transformations monosubstituted with formation polyphosphates proceed, established thermogravimetric method. determined using X-ray phase analysis. Quantitative applying original method eluent ion-exchange chromatography. It that basic products thermal range temperatures 200–650 °C Na 3 Р О 9 , 2 H P O 7 6 18 . Thermochemical NaH PO 4 into at 650 °C accompanied side reactions 10 We proposed chemical scheme Kinetics isothermal process obtaining from examined. quantitative inorganic depending duration dehydration. possibility a salt mixture assigned qualitative demonstrated. use mixture: 76 % 8 % 10, obtained 650 °C, as phosphate component lubricants for hot rolling pipes.

参考文章(17)
R. Amini, H. Vakili, B. Ramezanzadeh, Studying the effects of poly (vinyl) alcohol on the morphology and anti-corrosion performance of phosphate coating applied on steel surface Journal of The Taiwan Institute of Chemical Engineers. ,vol. 58, pp. 542- 551 ,(2016) , 10.1016/J.JTICE.2015.06.024
Therese M. McBeath, Enzo Lombi, Michael J. McLaughlin, Else K. Bünemann, Polyphosphate-fertilizer solution stability with time, temperature, and pH Journal of Plant Nutrition and Soil Science. ,vol. 170, pp. 387- 391 ,(2007) , 10.1002/JPLN.200625166
Khalid Abdalla, Rahmat Azmi, Aziz Azizan, The Effect of pH on Zinc Phosphate Coating Morphology and its Corrosion Resistance on Mild Steel Advanced Materials Research. ,vol. 626, pp. 569- 574 ,(2012) , 10.4028/WWW.SCIENTIFIC.NET/AMR.626.569
Tatyana V. Kulakovskaya, Vladimir M. Vagabov, Igor S. Kulaev, Inorganic polyphosphate in industry, agriculture and medicine: Modern state and outlook Process Biochemistry. ,vol. 47, pp. 1- 10 ,(2012) , 10.1016/J.PROCBIO.2011.10.028
Saeed Farrokhpay, Gayle E. Morris, Leanne G. Britcher, Stability of sodium polyphosphate dispersants in mineral processing applications Minerals Engineering. ,vol. 39, pp. 39- 44 ,(2012) , 10.1016/J.MINENG.2012.07.001
F. I. Danilov, I. V. Sknar, Yu. E. Sknar, Electroplating of Ni-Fe alloys from methanesulfonate electrolytes Russian Journal of Electrochemistry. ,vol. 50, pp. 293- 296 ,(2014) , 10.1134/S1023193514030045
Arash Momeni, Mark Joseph Filiaggi, Synthesis and characterization of different chain length sodium polyphosphates Journal of Non-crystalline Solids. ,vol. 382, pp. 11- 17 ,(2013) , 10.1016/J.JNONCRYSOL.2013.10.003
Célie Rulliere, Laurent Perenes, Daniel Senocq, Alain Dodi, Sylvie Marchesseau, Heat treatment effect on polyphosphate chain length in aqueous and calcium solutions. Food Chemistry. ,vol. 134, pp. 712- 716 ,(2012) , 10.1016/J.FOODCHEM.2012.02.164