Photocatalytic decomposition of mobile-source related pollutants using a continuous-flow reactor.
作者： Wan-Kuen Jo , Seung-Ho Shin
DOI: 10.1016/S1001-0742(09)60130-3
关键词: Photocatalysis 、 Adsorption 、 Degradation (geology) 、 Steady state (chemistry) 、 Pollutant 、 Environmental chemistry 、 Naphthalene 、 Relative humidity 、 Ultraviolet light 、 Chemistry
摘要: This study evaluated the application of a continuous-flow photocatalytic reactor for control two mobile-derived pollutants, methyl-tertiary butyl ether (MTBE) and naphthalene, present at in-vehicle levels. Variables tested this included hydraulic diameter (HD), stream flow rate (SFR), relative humidity (RH), feeding type (FT). The fixed parameters contaminant concentration, ultraviolet light source, weight TiO2. In all experimental conditions adsorption process reached equilibrium within 30 to 180 min target compounds, outlet concentrations oxidation (PCO) while operating steady state 60 min. degradation compounds was dependent on RH, HD, FT, or SFR. PCO system exhibited high (up nearly 100% certain conditions) mineralization efficiencies suggesting that can effectively be employed improve indoor air quality. Moreover, it confirmed trichloroethylene urban-ambient level also could enhance efficiency naphthalene when applying technology inside vehicles.
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sci-hub.se 参考文章(49)
Lisa Stevens, John A. Lanning, Larry G. Anderson, William A. Jacoby, Nicholas Chornet, Investigation of the Photocatalytic Oxidation of Low-Level Carbonyl Compounds Journal of The Air & Waste Management Association. ,vol. 48, pp. 979- 984 ,(1998) , 10.1080/10473289.1998.10463748
Zheng-hong Huang, Zhan-sheng Wang, Fei-yu Kang, Jun Liu, Gas phase trichloroethylene removal at low concentration using activated carbon fiber. Journal of Environmental Sciences-china. ,vol. 16, pp. 53- 55 ,(2004)
Bao-xiu ZHAO, Xiang-zhong LI, Peng WANG, Degradation of 2,4-dichlorophenol with a novel TiO2/Ti-Fe-graphite felt photoelectrocatalytic oxidation process. Journal of Environmental Sciences-china. ,vol. 19, pp. 1020- 1024 ,(2007) , 10.1016/S1001-0742(07)60165-X
Juan Zhao, Xudong Yang, None, Photocatalytic oxidation for indoor air purification: a literature review Building and Environment. ,vol. 38, pp. 645- 654 ,(2003) , 10.1016/S0360-1323(02)00212-3
Jin-Woo Lee, Wan-Kuen Jo, Actual commuter exposure to methyl-tertiary butyl ether, benzene and toluene while traveling in Korean urban areas Science of The Total Environment. ,vol. 291, pp. 219- 228 ,(2002) , 10.1016/S0048-9697(01)01101-9
Rufus D. Edwards, Christian Schweizer, Matti Jantunen, Hak Kan Lai, Lucy Bayer-Oglesby, Klea Katsouyanni, Mark Nieuwenhuijsen, Kristiina Saarela, Radim Sram, Nino Künzli, Personal exposures to VOC in the upper end of the distribution - Relationships to indoor, outdoor and workplace concentrations Atmospheric Environment. ,vol. 39, pp. 2299- 2307 ,(2005) , 10.1016/J.ATMOSENV.2004.12.026
Xianzhi Fu, Walter A. Zeltner, Marc A. Anderson, The gas-phase photocatalytic mineralization of benzene on porous titania-based catalysts Applied Catalysis B-environmental. ,vol. 6, pp. 209- 224 ,(1995) , 10.1016/0926-3373(95)00017-8
Stuart A Batterman, Chung-Yu Peng, James Braun, Levels and composition of volatile organic compounds on commuting routes in Detroit, Michigan Atmospheric Environment. ,vol. 36, pp. 6015- 6030 ,(2002) , 10.1016/S1352-2310(02)00770-7
F. Bertinchamps, A. Attianese, M.M. Mestdagh, E.M. Gaigneaux, Catalysts for chlorinated VOCs abatement: Multiple effects of water on the activity of VOx based catalysts for the combustion of chlorobenzene Catalysis Today. ,vol. 112, pp. 165- 168 ,(2006) , 10.1016/J.CATTOD.2005.11.043
J. Araña, A. Peña Alonso, J.M. Doña Rodríguez, J.A. Herrera Melián, O. González Díaz, J. Pérez Peña, Comparative study of MTBE photocatalytic degradation with TiO2 and Cu-TiO2 Applied Catalysis B-environmental. ,vol. 78, pp. 355- 363 ,(2008) , 10.1016/J.APCATB.2007.09.023