Chemo- and Regioselective Reductive Transposition of Allylic Alcohol Derivatives via Iridium or Rhodium Catalysis.

摘要: We report highly chemo- and regioselective reductive transpositions of methyl carbonates to furnish olefin products with complementary regioselectivity that established Pd-catalysis. These Rh- Ir-catalysed transformations proceed under mild conditions enable selective deoxygenation in the presence functional groups are susceptible reduction by metal hydrides.