Chemo- and regioselective reductive transposition of allylic alcohol derivatives via iridium or rhodium catalysis
作者： Rylan J. Lundgren , Bryce N. Thomas
DOI: 10.1039/C5CC07993D
关键词: Metal 、 Organic chemistry 、 Rhodium 、 Catalysis 、 Olefin fiber 、 Transposition (music) 、 Deoxygenation 、 Iridium 、 Chemistry 、 Regioselectivity
摘要: We report highly chemo- and regioselective reductive transpositions of methyl carbonates to furnish olefin products with complementary regioselectivity that established Pd-catalysis. These Rh- Ir-catalysed transformations proceed under mild conditions enable selective deoxygenation in the presence functional groups are susceptible reduction by metal hydrides.
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