Synthesis and Crystal Structure of A Novel Polymeric Manganese(IV) Complex Derived From the Schiff Base 2-Ethoxy-6-[(2-hydroxyethylimino)methyl]phenol
作者： De-Suo Yang
DOI: 10.1080/15533174.2012.684228
关键词: Sodium azide 、 Schiff base 、 Alkoxy group 、 Crystal structure 、 Manganese 、 Chemistry 、 Infrared spectroscopy 、 Phenol 、 Methanol 、 Polymer chemistry 、 Inorganic chemistry
摘要: A novel polymeric manganese(IV) complex, [Mn(L)(HL)(N3)] n ·nCH3OH, has been synthesized from the Schiff base 2-ethoxy-6-[(2-hydroxyethylimino)methyl]phenol (H2L) with manganese chloride and sodium azide in methanol. The complex was characterized by elemental analysis, IR spectrum, single-crystal X-ray diffraction. Mn atom is coordinated two phenolic oxygen, imino nitrogen, one hydroxyl oxygen atoms ligands, azido N atom, giving an octahedral coordination.
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