Rotationally specific rates of vibration–vibration energy exchange in collisions of NO(X 2Π1/2,v=3) with NO(X 2Π,v=0)
作者： Meezanul Islam , Ian W. M. Smith
DOI: 10.1063/1.479843
关键词: Atomic physics 、 Line (formation) 、 Ultraviolet 、 Spectral line 、 Fluorescence 、 Optical parametric oscillator 、 Excited state 、 Chemistry 、 Resonance 、 Infrared
摘要: Infrared ultraviolet double resonance (IRUVDR) experiments have been performed to investigate the rotational specificity of vibrational–vibrational (V–V) exchange process, NO(X 2Π1/2,v=3,Ji)+NO(v=0)→NO(X 2Π1/2,v=2,Jf)+NO(v=1), for which vibrational energy discrepancy corresponds 55.9 cm−1. Radiation from an optical parametric oscillator was used excite NO molecules into a specific level (Ji) in X 2Π, Ω=12, v=3 state. Laser-induced fluorescence (LIF) spectra (0,2) band A 2Σ+–X 2Π1/2 system were then recorded at delays corresponding fraction collision. From relative line intensities, rate coefficients determined transfer excited molecule X 2Π1/2, v=3, Ji different final levels (Jf) v=2 Results are reported Ji=3.5, 4.5, 7.5, 10.5, and 15.5. The data show significant, though not strong, propensity J decrease by one; i.e., ΔJ=Jf−Ji=−1, especially higher lev...
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sci-hub.se 参考文章(30)
James T. Yardley, Introduction to Molecular Energy Transfer ,(1980)
Aa. S. Sudbo/, M. M. T. Loy, Measurement of absolute state‐to‐state rate constants for collision‐induced transitions between spin‐orbit and rotational states of NO(X 2Π, v = 2) Journal of Chemical Physics. ,vol. 76, pp. 3646- 3654 ,(1982) , 10.1063/1.443402
Michael J. Frost, Energy transfer in the 31,214151 Fermi‐resonant states of acetylene. I. Rotational energy transfer Journal of Chemical Physics. ,vol. 98, pp. 8572- 8579 ,(1993) , 10.1063/1.464517
T. A. Dillon, J. C. Stephenson, Effect of the straight path approximation and exchange forces on vibrational energy transfer The Journal of Chemical Physics. ,vol. 58, pp. 3849- 3854 ,(1973) , 10.1063/1.1679739
Meezanul Islam, Ian W. M. Smith, Jörg W. Wiebrecht, Rate coefficients for state‐to‐state rovibronic relaxation in collisions between NO(X 2Π, ν=2, Ω, J) and NO, He, and Ar at 295, 200, and 80 K Journal of Chemical Physics. ,vol. 103, pp. 9676- 9691 ,(1995) , 10.1063/1.469983
J.A. Dodd, S.M. Singleton, S.M. Miller, P.S. Armstrong, W.A.M. Blumberg, Vibrational relaxation of NO(ν = 2, 3) by atomic oxygen Chemical Physics Letters. ,vol. 260, pp. 103- 108 ,(1996) , 10.1016/0009-2614(96)00851-2
Philip L. James, Ian R. Sims, Ian W.M. Smith, Total and state-to-state rate coefficients for rotational energy transfer in collisions between NO(X2Π) and He at temperatures down to 15 K Chemical Physics Letters. ,vol. 272, pp. 412- 418 ,(1997) , 10.1016/S0009-2614(97)00539-3
Enrique Cuellar, John H. Parker, George C. Pimentel, Rotational chemical lasers from hydrogen fluoride elimination reactions Journal of Chemical Physics. ,vol. 61, pp. 422- 423 ,(1974) , 10.1063/1.1681656
C. P. Bewick, J. F. Martins, B. J. Orr, Rotationally specific mode–to–mode vibrational energy transfer in D2CO/D2CO collisions. II. Kinetics and modeling Journal of Chemical Physics. ,vol. 93, pp. 8643- 8657 ,(1990) , 10.1063/1.459251
Bruce H. Mahan, Resonant Transfer of Vibrational Energy in Molecular Collisions The Journal of Chemical Physics. ,vol. 46, pp. 98- 101 ,(1967) , 10.1063/1.1840437