Resonant Transfer of Vibrational Energy in Molecular Collisions
作者： Bruce H. Mahan
DOI: 10.1063/1.1840437
关键词:
摘要: The cross section for resonant vibration—vibration energy exchange between infrared‐active molecules due to the long‐range dipole potential is formulated. It found that despite certain restrictions imposed by rotational selection rules, energy‐exchange sections may be as much 0.01 0.1 times large molecular gas‐kinetic and are greater than those estimated using only an exponential repulsive interaction molecules.
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