Molecular complexes of phenols with DDQ
作者： T. Vinod Kumar , T. Veeraiah , G. Venkateshwarlu
DOI: 10.1007/BF02704313
关键词: Molecular orbital 、 Absorption (chemistry) 、 Solvent 、 Chemistry 、 Photochemistry 、 Phenols 、 Ionization 、 Substituent 、 Acceptor 、 Atmospheric temperature range
摘要: Molecular complexes of phenols with DDQ have been studied spectrophotometrically in the temperature range 10–30‡C a solvent (CHC13) low polarity under donor concentrations. All exhibit one CT band each wavelength region where acceptor and do not any absorption. The are inferred to be π2π type Ry configuration which molecular orbital encompasses substituent. ionization potentials donors, stability constants thermodynamic parameters evaluated.
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